Inclusion of metal complexes into cavities of 2D coordination networks built from p-sulfonatothiacalix[4]arene tetranuclear clusters

Mingyan Wu; Daqiang Yuan; Lei Han; Benlai Wu; Yanqing Xu; Maochun Hong

doi:10.1002/ejic.200500863

Inclusion of metal complexes into cavities of 2D coordination networks built from p-sulfonatothiacalix[4]arene tetranuclear clusters

Mingyan Wu
, Daqiang Yuan
, Lei Han
, Benlai Wu
, Yanqing Xu
, Maochun Hong^*

^*此作品的通讯作者

CAS - Fujian Institute of Research on the Structure of Matter

科研成果: 期刊稿件 › 文章 › 同行评审

14 引用（Scopus）

摘要

Reactions of the p-sulfonatothiacalix[4]arene salt (Na₄H ₄TCAS) and MSO₄ (M = Co, Cu) in the presence of 2,2′-bipyrazine (2,2′-bpz) generated 2D coordination networks formed by tetranuclear cluster subunits, namely {[Co(2,2′-bpz)(H ₂O)₄]²⁺C[Co₄(TCAS)(μ₄- SO₄)(H₂O)₄]^2-· 10.75H ₂O}_n (1) and ([Cu(2,2′-bpz)(H₂O) ₃]²⁺C[Cu₄(TCAS)(μ₄-SO ₄)(H₂O)₄]^2-·16H ₂O}_n (2). X-ray diffraction analyses reveal that both these complexes include metal-2,2′-bipyrazine complexes into the hydrophobic cavities of p-sulfonatothiacalix[4]arenes as guests through supramolecular interactions.

源语言	英语
页（从-至）	526-530
页数	5
期刊	European Journal of Inorganic Chemistry
期	3
DOI	https://doi.org/10.1002/ejic.200500863
出版状态	已出版 - 6 2月 2006
已对外发布	是

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@article{be69b6eaee6b44e5817453b39927a40f,

title = "Inclusion of metal complexes into cavities of 2D coordination networks built from p-sulfonatothiacalix[4]arene tetranuclear clusters",

abstract = "Reactions of the p-sulfonatothiacalix[4]arene salt (Na4H 4TCAS) and MSO4 (M = Co, Cu) in the presence of 2,2′-bipyrazine (2,2′-bpz) generated 2D coordination networks formed by tetranuclear cluster subunits, namely \{[Co(2,2′-bpz)(H 2O)4]2+C[Co4(TCAS)(μ4- SO4)(H2O)4]2-· 10.75H 2O\}n (1) and ([Cu(2,2′-bpz)(H2O) 3]2+C[Cu4(TCAS)(μ4-SO 4)(H2O)4]2-·16H 2O\}n (2). X-ray diffraction analyses reveal that both these complexes include metal-2,2′-bipyrazine complexes into the hydrophobic cavities of p-sulfonatothiacalix[4]arenes as guests through supramolecular interactions.",

keywords = "Coordination polymer, Inclusion, Supramolecular chemistry, p-Sulfonatothiacalix[4]arene",

author = "Mingyan Wu and Daqiang Yuan and Lei Han and Benlai Wu and Yanqing Xu and Maochun Hong",

year = "2006",

month = feb,

day = "6",

doi = "10.1002/ejic.200500863",

language = "English",

pages = "526--530",

journal = "European Journal of Inorganic Chemistry",

issn = "1434-1948",

publisher = "Wiley-VCH Verlag",

number = "3",

}

TY - JOUR

T1 - Inclusion of metal complexes into cavities of 2D coordination networks built from p-sulfonatothiacalix[4]arene tetranuclear clusters

AU - Wu, Mingyan

AU - Yuan, Daqiang

AU - Han, Lei

AU - Wu, Benlai

AU - Xu, Yanqing

AU - Hong, Maochun

PY - 2006/2/6

Y1 - 2006/2/6

N2 - Reactions of the p-sulfonatothiacalix[4]arene salt (Na4H 4TCAS) and MSO4 (M = Co, Cu) in the presence of 2,2′-bipyrazine (2,2′-bpz) generated 2D coordination networks formed by tetranuclear cluster subunits, namely {[Co(2,2′-bpz)(H 2O)4]2+C[Co4(TCAS)(μ4- SO4)(H2O)4]2-· 10.75H 2O}n (1) and ([Cu(2,2′-bpz)(H2O) 3]2+C[Cu4(TCAS)(μ4-SO 4)(H2O)4]2-·16H 2O}n (2). X-ray diffraction analyses reveal that both these complexes include metal-2,2′-bipyrazine complexes into the hydrophobic cavities of p-sulfonatothiacalix[4]arenes as guests through supramolecular interactions.

AB - Reactions of the p-sulfonatothiacalix[4]arene salt (Na4H 4TCAS) and MSO4 (M = Co, Cu) in the presence of 2,2′-bipyrazine (2,2′-bpz) generated 2D coordination networks formed by tetranuclear cluster subunits, namely {[Co(2,2′-bpz)(H 2O)4]2+C[Co4(TCAS)(μ4- SO4)(H2O)4]2-· 10.75H 2O}n (1) and ([Cu(2,2′-bpz)(H2O) 3]2+C[Cu4(TCAS)(μ4-SO 4)(H2O)4]2-·16H 2O}n (2). X-ray diffraction analyses reveal that both these complexes include metal-2,2′-bipyrazine complexes into the hydrophobic cavities of p-sulfonatothiacalix[4]arenes as guests through supramolecular interactions.

KW - Coordination polymer

KW - Inclusion

KW - Supramolecular chemistry

KW - p-Sulfonatothiacalix[4]arene

UR - https://www.scopus.com/pages/publications/32544454995

U2 - 10.1002/ejic.200500863

DO - 10.1002/ejic.200500863

M3 - Article

AN - SCOPUS:32544454995

SN - 1434-1948

SP - 526

EP - 530

JO - European Journal of Inorganic Chemistry

JF - European Journal of Inorganic Chemistry

IS - 3

ER -

Inclusion of metal complexes into cavities of 2D coordination networks built from p-sulfonatothiacalix[4]arene tetranuclear clusters

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