In situ ligand reactions under hydrothermal conditions afford a novel zinc-substituted polyoxovanadate dimer

Shou Tian Zheng; Ming Hui Wang; Guo Yu Yang

doi:10.1021/ic700562m

In situ ligand reactions under hydrothermal conditions afford a novel zinc-substituted polyoxovanadate dimer

Shou Tian Zheng
, Ming Hui Wang
, Guo Yu Yang^*

^*此作品的通讯作者

CAS - Fujian Institute of Research on the Structure of Matter
Qingdao University of Science and Technology

科研成果: 期刊稿件 › 文章 › 同行评审

74 引用（Scopus）

摘要

A novel polyoxovanadate (POV), [Zn(2,2′-bpy)₃] ₄[(ppz){{Zn(tepa)}₂ZnAs₈V₁₃O ₄₁(H₂O)}₂][As₈V₁₄O ₄₂(0.5H₂O)]₂·4H₂O (1, 2,2′-bpy = 2,2′-bipyridine, ppz = piperazine, tepa = tetraethylenepentamine), has been hydrothermally synthesized and structurally characterized by elemental analysis, IR spectra, thermogravimetric analysis, magnetic measurement, and single-crystal X-ray diffraction analysis. Crystal data for 1: orthorhombic, Aba2, a = 28.3414(14) Å, b = 27.9995(16) Å, c = 41.5819(16) Å, V = 32997(3) Å³, Z = 4, ρ = 2.264 mg·cm^-3. X-ray structure analysis shows that the structure of 1 consists of one unique zinc-substituted POV dimer and two POV monomers. Interestingly, the formation of the zinc-substituted POV dimer involves two new in situ ligand reactions under hydrothermal conditions, the intermolecular and intramolecular deamination coupling reactions of dien. Magnetization measurement revealed the presence of antiferromagnetic interaction between V^IV ions in 1.

源语言	英语
页（从-至）	9503-9508
页数	6
期刊	Inorganic Chemistry
卷	46
期	22
DOI	https://doi.org/10.1021/ic700562m
出版状态	已出版 - 29 10月 2007
已对外发布	是

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@article{d4a79f5bbbac448f80bd13b8ff8e46a2,

title = "In situ ligand reactions under hydrothermal conditions afford a novel zinc-substituted polyoxovanadate dimer",

abstract = "A novel polyoxovanadate (POV), [Zn(2,2′-bpy)3] 4[(ppz)\{\{Zn(tepa)\}2ZnAs8V13O 41(H2O)\}2][As8V14O 42(0.5H2O)]2·4H2O (1, 2,2′-bpy = 2,2′-bipyridine, ppz = piperazine, tepa = tetraethylenepentamine), has been hydrothermally synthesized and structurally characterized by elemental analysis, IR spectra, thermogravimetric analysis, magnetic measurement, and single-crystal X-ray diffraction analysis. Crystal data for 1: orthorhombic, Aba2, a = 28.3414(14) {\AA}, b = 27.9995(16) {\AA}, c = 41.5819(16) {\AA}, V = 32997(3) {\AA}3, Z = 4, ρ = 2.264 mg·cm-3. X-ray structure analysis shows that the structure of 1 consists of one unique zinc-substituted POV dimer and two POV monomers. Interestingly, the formation of the zinc-substituted POV dimer involves two new in situ ligand reactions under hydrothermal conditions, the intermolecular and intramolecular deamination coupling reactions of dien. Magnetization measurement revealed the presence of antiferromagnetic interaction between VIV ions in 1.",

author = "Zheng, \{Shou Tian\} and Wang, \{Ming Hui\} and Yang, \{Guo Yu\}",

year = "2007",

month = oct,

day = "29",

doi = "10.1021/ic700562m",

language = "English",

volume = "46",

pages = "9503--9508",

journal = "Inorganic Chemistry",

issn = "0020-1669",

publisher = "American Chemical Society",

number = "22",

}

TY - JOUR

T1 - In situ ligand reactions under hydrothermal conditions afford a novel zinc-substituted polyoxovanadate dimer

AU - Zheng, Shou Tian

AU - Wang, Ming Hui

AU - Yang, Guo Yu

PY - 2007/10/29

Y1 - 2007/10/29

N2 - A novel polyoxovanadate (POV), [Zn(2,2′-bpy)3] 4[(ppz){{Zn(tepa)}2ZnAs8V13O 41(H2O)}2][As8V14O 42(0.5H2O)]2·4H2O (1, 2,2′-bpy = 2,2′-bipyridine, ppz = piperazine, tepa = tetraethylenepentamine), has been hydrothermally synthesized and structurally characterized by elemental analysis, IR spectra, thermogravimetric analysis, magnetic measurement, and single-crystal X-ray diffraction analysis. Crystal data for 1: orthorhombic, Aba2, a = 28.3414(14) Å, b = 27.9995(16) Å, c = 41.5819(16) Å, V = 32997(3) Å3, Z = 4, ρ = 2.264 mg·cm-3. X-ray structure analysis shows that the structure of 1 consists of one unique zinc-substituted POV dimer and two POV monomers. Interestingly, the formation of the zinc-substituted POV dimer involves two new in situ ligand reactions under hydrothermal conditions, the intermolecular and intramolecular deamination coupling reactions of dien. Magnetization measurement revealed the presence of antiferromagnetic interaction between VIV ions in 1.

AB - A novel polyoxovanadate (POV), [Zn(2,2′-bpy)3] 4[(ppz){{Zn(tepa)}2ZnAs8V13O 41(H2O)}2][As8V14O 42(0.5H2O)]2·4H2O (1, 2,2′-bpy = 2,2′-bipyridine, ppz = piperazine, tepa = tetraethylenepentamine), has been hydrothermally synthesized and structurally characterized by elemental analysis, IR spectra, thermogravimetric analysis, magnetic measurement, and single-crystal X-ray diffraction analysis. Crystal data for 1: orthorhombic, Aba2, a = 28.3414(14) Å, b = 27.9995(16) Å, c = 41.5819(16) Å, V = 32997(3) Å3, Z = 4, ρ = 2.264 mg·cm-3. X-ray structure analysis shows that the structure of 1 consists of one unique zinc-substituted POV dimer and two POV monomers. Interestingly, the formation of the zinc-substituted POV dimer involves two new in situ ligand reactions under hydrothermal conditions, the intermolecular and intramolecular deamination coupling reactions of dien. Magnetization measurement revealed the presence of antiferromagnetic interaction between VIV ions in 1.

UR - https://www.scopus.com/pages/publications/35848931477

U2 - 10.1021/ic700562m

DO - 10.1021/ic700562m

M3 - Article

AN - SCOPUS:35848931477

SN - 0020-1669

VL - 46

SP - 9503

EP - 9508

JO - Inorganic Chemistry

JF - Inorganic Chemistry

IS - 22

ER -

In situ ligand reactions under hydrothermal conditions afford a novel zinc-substituted polyoxovanadate dimer

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