Hydrothermal synthesis and structure of one new polyoxotungsate[Ni(trien)] 4[Ni4(H2O)2(HPW9O 34)2]·4H2P

Dan Zhao; Shou Tian Zheng; Guo Yua Yang

Hydrothermal synthesis and structure of one new polyoxotungsate[Ni(trien)] ₄[Ni₄(H₂O)₂(HPW₉O ₃₄)2]·4H₂P

Dan Zhao
, Shou Tian Zheng
, Guo Yua Yang

CAS - Fujian Institute of Research on the Structure of Matter
Fujian Normal University

科研成果: 期刊稿件 › 文章 › 同行评审

摘要

One new sandwich-type tetra-nickel substituted polyoxotungsate, [Ni(trien)]_4-[Ni₄(H₂O)₂(HPW ₉O₃₄)₂]̇4H₂O (1, trien = triethylenetetramine), has been hydrothermally synthesized and characterized by IR, elemental analysis, TGA, and single-crystal X-ray diffraction analysis. Crystal data for 1: triclinic, space group P1̄ with a = 13.279(3), b = 13.816(3), c = 14.494(4) Å, α = 95.403(1), β = 113.173(4), γ = 93.809(3)°, V= 2418.0(10) Å³, Z = 1 and D ^c = 3.861 g/cm³. X-ray crystallographic study shows that compound 1 is a relatively rare inorganic-organic hybrid polyoxo tungstate constructed from sandwich Ni-substituted polyoxo- anions and nickel complexes.

源语言	英语
页（从-至）	74-80
页数	7
期刊	Jiegou Huaxue
卷	29
期	1
出版状态	已出版 - 2010
已对外发布	是

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引用此

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title = "Hydrothermal synthesis and structure of one new polyoxotungsate[Ni(trien)] 4[Ni4(H2O)2(HPW9O 34)2]·4H2P",

abstract = "One new sandwich-type tetra-nickel substituted polyoxotungsate, [Ni(trien)]4-[Ni4(H2O)2(HPW 9O34)2{\.]}4H2O (1, trien = triethylenetetramine), has been hydrothermally synthesized and characterized by IR, elemental analysis, TGA, and single-crystal X-ray diffraction analysis. Crystal data for 1: triclinic, space group P{\=1} with a = 13.279(3), b = 13.816(3), c = 14.494(4) {\AA}, α = 95.403(1), β = 113.173(4), γ = 93.809(3)°, V= 2418.0(10) {\AA}3, Z = 1 and D c = 3.861 g/cm3. X-ray crystallographic study shows that compound 1 is a relatively rare inorganic-organic hybrid polyoxo tungstate constructed from sandwich Ni-substituted polyoxo- anions and nickel complexes.",

keywords = "Crystal structure, Polyoxotungstate, Substitute, Transition metal",

author = "Dan Zhao and Zheng, \{Shou Tian\} and Yang, \{Guo Yua\}",

year = "2010",

language = "English",

volume = "29",

pages = "74--80",

journal = "Jiegou Huaxue",

issn = "0254-5861",

publisher = "Fujian Institute of Research of the Structure of Matter",

number = "1",

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TY - JOUR

T1 - Hydrothermal synthesis and structure of one new polyoxotungsate[Ni(trien)] 4[Ni4(H2O)2(HPW9O 34)2]·4H2P

AU - Zhao, Dan

AU - Zheng, Shou Tian

AU - Yang, Guo Yua

PY - 2010

Y1 - 2010

N2 - One new sandwich-type tetra-nickel substituted polyoxotungsate, [Ni(trien)]4-[Ni4(H2O)2(HPW 9O34)2]̇4H2O (1, trien = triethylenetetramine), has been hydrothermally synthesized and characterized by IR, elemental analysis, TGA, and single-crystal X-ray diffraction analysis. Crystal data for 1: triclinic, space group P1̄ with a = 13.279(3), b = 13.816(3), c = 14.494(4) Å, α = 95.403(1), β = 113.173(4), γ = 93.809(3)°, V= 2418.0(10) Å3, Z = 1 and D c = 3.861 g/cm3. X-ray crystallographic study shows that compound 1 is a relatively rare inorganic-organic hybrid polyoxo tungstate constructed from sandwich Ni-substituted polyoxo- anions and nickel complexes.

AB - One new sandwich-type tetra-nickel substituted polyoxotungsate, [Ni(trien)]4-[Ni4(H2O)2(HPW 9O34)2]̇4H2O (1, trien = triethylenetetramine), has been hydrothermally synthesized and characterized by IR, elemental analysis, TGA, and single-crystal X-ray diffraction analysis. Crystal data for 1: triclinic, space group P1̄ with a = 13.279(3), b = 13.816(3), c = 14.494(4) Å, α = 95.403(1), β = 113.173(4), γ = 93.809(3)°, V= 2418.0(10) Å3, Z = 1 and D c = 3.861 g/cm3. X-ray crystallographic study shows that compound 1 is a relatively rare inorganic-organic hybrid polyoxo tungstate constructed from sandwich Ni-substituted polyoxo- anions and nickel complexes.

KW - Crystal structure

KW - Polyoxotungstate

KW - Substitute

KW - Transition metal

UR - https://www.scopus.com/pages/publications/77149179068

M3 - Article

AN - SCOPUS:77149179068

SN - 0254-5861

VL - 29

SP - 74

EP - 80

JO - Jiegou Huaxue

JF - Jiegou Huaxue

IS - 1

ER -

Hydrothermal synthesis and structure of one new polyoxotungsate[Ni(trien)] 4[Ni4(H2O)2(HPW9O 34)2]·4H2P

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Hydrothermal synthesis and structure of one new polyoxotungsate[Ni(trien)] ₄[Ni₄(H₂O)₂(HPW₉O ₃₄)2]·4H₂P