Hydrothermal synthesis and structure of a new arsenic-vanadium cluster: [NH 2(CH 2CH 2) 2NH 2] 3[As 8V 14O 42(SO 4)] ·6.5H 2O

Shou Tian Zheng; Jie Zhang; Guo Yu Yang

doi:10.1016/j.molstruc.2004.06.026

Hydrothermal synthesis and structure of a new arsenic-vanadium cluster: [NH ₂(CH ₂CH ₂) ₂NH ₂] ₃[As ₈V ₁₄O ₄₂(SO ₄)] ·6.5H ₂O

Shou Tian Zheng
, Jie Zhang
, Guo Yu Yang

CAS - Fujian Institute of Research on the Structure of Matter
Nanjing University

科研成果: 期刊稿件 › 文章 › 同行评审

11 引用（Scopus）

摘要

A new arsenic-vanadium clusters, [NH ₂(CH ₂CH ₂) ₂NH ₂] ₃[As ₈V ₁₄O ₄₂(SO ₄)]·6.5H ₂O (1), have been hydrothermally synthesized and characterized by IR, elemental analysis, TGA, magnetic property, and single crystal X-ray diffraction analysis. Crystal data: Monoclinic, P2(1)/n, a=21.963(2) Å, b=14.508(1) Å, c=23.054(3) Å, β=118.316(3)°, Z=4. X-ray crystallographic study showed that crystal 1 is composed of the discrete cluster anions [As ₈V ₁₄O ₄₂(SO ₄)] ^6-, organic amine molecules providing charge-compensation, space-filling, and structure-directing roles, and lattice water molecules occupying in the structure. The study of the magnetic susceptibility of 1 demonstrates the presence of antiferromagnetic interaction between V ^IV cations in 1.

源语言	英语
页（从-至）	127-132
页数	6
期刊	Journal of Molecular Structure
卷	705
期	1-3
DOI	https://doi.org/10.1016/j.molstruc.2004.06.026
出版状态	已出版 - 1 11月 2004
已对外发布	是

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10.1016/j.molstruc.2004.06.026

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@article{e34ac905289d4e97a5c9253cd4a3e42b,

title = "Hydrothermal synthesis and structure of a new arsenic-vanadium cluster: [NH 2(CH 2CH 2) 2NH 2] 3[As 8V 14O 42(SO 4)] ·6.5H 2O",

abstract = "A new arsenic-vanadium clusters, [NH 2(CH 2CH 2) 2NH 2] 3[As 8V 14O 42(SO 4)]·6.5H 2O (1), have been hydrothermally synthesized and characterized by IR, elemental analysis, TGA, magnetic property, and single crystal X-ray diffraction analysis. Crystal data: Monoclinic, P2(1)/n, a=21.963(2) {\AA}, b=14.508(1) {\AA}, c=23.054(3) {\AA}, β=118.316(3)°, Z=4. X-ray crystallographic study showed that crystal 1 is composed of the discrete cluster anions [As 8V 14O 42(SO 4)] 6-, organic amine molecules providing charge-compensation, space-filling, and structure-directing roles, and lattice water molecules occupying in the structure. The study of the magnetic susceptibility of 1 demonstrates the presence of antiferromagnetic interaction between V IV cations in 1.",

keywords = "Arsenic, Crystal structure, Hydrothermal synthesis, Polyoxometalate, Vanadium",

author = "Zheng, \{Shou Tian\} and Jie Zhang and Yang, \{Guo Yu\}",

year = "2004",

month = nov,

day = "1",

doi = "10.1016/j.molstruc.2004.06.026",

language = "English",

volume = "705",

pages = "127--132",

journal = "Journal of Molecular Structure",

issn = "0022-2860",

publisher = "Elsevier B.V.",

number = "1-3",

}

TY - JOUR

T1 - Hydrothermal synthesis and structure of a new arsenic-vanadium cluster

T2 - [NH 2(CH 2CH 2) 2NH 2] 3[As 8V 14O 42(SO 4)] ·6.5H 2O

AU - Zheng, Shou Tian

AU - Zhang, Jie

AU - Yang, Guo Yu

PY - 2004/11/1

Y1 - 2004/11/1

N2 - A new arsenic-vanadium clusters, [NH 2(CH 2CH 2) 2NH 2] 3[As 8V 14O 42(SO 4)]·6.5H 2O (1), have been hydrothermally synthesized and characterized by IR, elemental analysis, TGA, magnetic property, and single crystal X-ray diffraction analysis. Crystal data: Monoclinic, P2(1)/n, a=21.963(2) Å, b=14.508(1) Å, c=23.054(3) Å, β=118.316(3)°, Z=4. X-ray crystallographic study showed that crystal 1 is composed of the discrete cluster anions [As 8V 14O 42(SO 4)] 6-, organic amine molecules providing charge-compensation, space-filling, and structure-directing roles, and lattice water molecules occupying in the structure. The study of the magnetic susceptibility of 1 demonstrates the presence of antiferromagnetic interaction between V IV cations in 1.

AB - A new arsenic-vanadium clusters, [NH 2(CH 2CH 2) 2NH 2] 3[As 8V 14O 42(SO 4)]·6.5H 2O (1), have been hydrothermally synthesized and characterized by IR, elemental analysis, TGA, magnetic property, and single crystal X-ray diffraction analysis. Crystal data: Monoclinic, P2(1)/n, a=21.963(2) Å, b=14.508(1) Å, c=23.054(3) Å, β=118.316(3)°, Z=4. X-ray crystallographic study showed that crystal 1 is composed of the discrete cluster anions [As 8V 14O 42(SO 4)] 6-, organic amine molecules providing charge-compensation, space-filling, and structure-directing roles, and lattice water molecules occupying in the structure. The study of the magnetic susceptibility of 1 demonstrates the presence of antiferromagnetic interaction between V IV cations in 1.

KW - Arsenic

KW - Crystal structure

KW - Hydrothermal synthesis

KW - Polyoxometalate

KW - Vanadium

UR - https://www.scopus.com/pages/publications/4444311405

U2 - 10.1016/j.molstruc.2004.06.026

DO - 10.1016/j.molstruc.2004.06.026

M3 - Article

AN - SCOPUS:4444311405

SN - 0022-2860

VL - 705

SP - 127

EP - 132

JO - Journal of Molecular Structure

JF - Journal of Molecular Structure

IS - 1-3

ER -

Hydrothermal synthesis and structure of a new arsenic-vanadium cluster: [NH 2(CH 2CH 2) 2NH 2] 3[As 8V 14O 42(SO 4)] ·6.5H 2O

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Hydrothermal synthesis and structure of a new arsenic-vanadium cluster: [NH ₂(CH ₂CH ₂) ₂NH ₂] ₃[As ₈V ₁₄O ₄₂(SO ₄)] ·6.5H ₂O