Hydrothermal synthesis and structural characterization of two 1-D and 2-D Dawson-based phosphotungstates

Jun Wei Zhao; Shou Tian Zheng; Wei Liu; Guo Yu Yang

doi:10.1016/j.jssc.2008.01.002

Hydrothermal synthesis and structural characterization of two 1-D and 2-D Dawson-based phosphotungstates

Jun Wei Zhao
, Shou Tian Zheng
, Wei Liu
, Guo Yu Yang^*

^*此作品的通讯作者

CAS - Fujian Institute of Research on the Structure of Matter
Shandong University of Technology

科研成果: 期刊稿件 › 文章 › 同行评审

24 引用（Scopus）

摘要

Two new Dawson-based phosphotungstates (H₂en)_0.5H[Cu(en)₂(H₂O)]₂{[Cu(en)₂](α₁-P₂W₁₇CuO₆₁)}·8H₂O (1) (en=ethylenediamine) and [4,4′-H₂bpy]₂{[Cu(4,4′-bpy)₃][Cu(4,4′-bpy)₄(H₂O)₂]₂[Cu(4,4′-bpy)][α-P₂W₁₈O₆₂]₂}·6H₂O (2) (4,4′-bpy=4,4′-bipyridine) have been hydrothermally synthesized and structurally characterized. 1 crystallizes in the triclinic space group P-1 with a=11.7626(17), b=13.246(2), c=29.350(5) Å, α=87.355(5), β=79.583(5), γ=66.993(3)°, V=4138.3(11) Å³, Z=2, GOF=1.089, R₁=0.0563 and wR₂=0.1505, whereas 2 belongs to the orthorhombic space group Iba2 with a=22.277(8), b=47.04(2), c=22.153(8) Å, V=23215(17) Å³, Z=4, GOF=1.051, R₁=0.0627 and wR₂=0.1477. 1 consists of a 1-D linear chain structure constructed from monocopper^II-substituted Dawson polyoxoanions, while 2 represents the first 2-D sheet-like structure with a (4,4)-connected topological net built up from plenary Dawson-type polyoxoanions and Cu^II-4,4′-bpy complex cations in polyoxometalate chemistry.

源语言	英语
页（从-至）	637-645
页数	9
期刊	Journal of Solid State Chemistry
卷	181
期	3
DOI	https://doi.org/10.1016/j.jssc.2008.01.002
出版状态	已出版 - 3月 2008
已对外发布	是

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@article{aac1b0e4fbe5458e9ac1b2a2a401ed5a,

title = "Hydrothermal synthesis and structural characterization of two 1-D and 2-D Dawson-based phosphotungstates",

abstract = "Two new Dawson-based phosphotungstates (H2en)0.5H[Cu(en)2(H2O)]2\{[Cu(en)2](α1-P2W17CuO61)\}·8H2O (1) (en=ethylenediamine) and [4,4′-H2bpy]2\{[Cu(4,4′-bpy)3][Cu(4,4′-bpy)4(H2O)2]2[Cu(4,4′-bpy)][α-P2W18O62]2\}·6H2O (2) (4,4′-bpy=4,4′-bipyridine) have been hydrothermally synthesized and structurally characterized. 1 crystallizes in the triclinic space group P-1 with a=11.7626(17), b=13.246(2), c=29.350(5) {\AA}, α=87.355(5), β=79.583(5), γ=66.993(3)°, V=4138.3(11) {\AA}3, Z=2, GOF=1.089, R1=0.0563 and wR2=0.1505, whereas 2 belongs to the orthorhombic space group Iba2 with a=22.277(8), b=47.04(2), c=22.153(8) {\AA}, V=23215(17) {\AA}3, Z=4, GOF=1.051, R1=0.0627 and wR2=0.1477. 1 consists of a 1-D linear chain structure constructed from monocopperII-substituted Dawson polyoxoanions, while 2 represents the first 2-D sheet-like structure with a (4,4)-connected topological net built up from plenary Dawson-type polyoxoanions and CuII-4,4′-bpy complex cations in polyoxometalate chemistry.",

keywords = "Copper, Dawson structure, Hydrothermal reaction, Polyoxometalates",

author = "Zhao, \{Jun Wei\} and Zheng, \{Shou Tian\} and Wei Liu and Yang, \{Guo Yu\}",

year = "2008",

month = mar,

doi = "10.1016/j.jssc.2008.01.002",

language = "English",

volume = "181",

pages = "637--645",

journal = "Journal of Solid State Chemistry",

issn = "0022-4596",

publisher = "Academic Press Inc.",

number = "3",

}

TY - JOUR

T1 - Hydrothermal synthesis and structural characterization of two 1-D and 2-D Dawson-based phosphotungstates

AU - Zhao, Jun Wei

AU - Zheng, Shou Tian

AU - Liu, Wei

AU - Yang, Guo Yu

PY - 2008/3

Y1 - 2008/3

N2 - Two new Dawson-based phosphotungstates (H2en)0.5H[Cu(en)2(H2O)]2{[Cu(en)2](α1-P2W17CuO61)}·8H2O (1) (en=ethylenediamine) and [4,4′-H2bpy]2{[Cu(4,4′-bpy)3][Cu(4,4′-bpy)4(H2O)2]2[Cu(4,4′-bpy)][α-P2W18O62]2}·6H2O (2) (4,4′-bpy=4,4′-bipyridine) have been hydrothermally synthesized and structurally characterized. 1 crystallizes in the triclinic space group P-1 with a=11.7626(17), b=13.246(2), c=29.350(5) Å, α=87.355(5), β=79.583(5), γ=66.993(3)°, V=4138.3(11) Å3, Z=2, GOF=1.089, R1=0.0563 and wR2=0.1505, whereas 2 belongs to the orthorhombic space group Iba2 with a=22.277(8), b=47.04(2), c=22.153(8) Å, V=23215(17) Å3, Z=4, GOF=1.051, R1=0.0627 and wR2=0.1477. 1 consists of a 1-D linear chain structure constructed from monocopperII-substituted Dawson polyoxoanions, while 2 represents the first 2-D sheet-like structure with a (4,4)-connected topological net built up from plenary Dawson-type polyoxoanions and CuII-4,4′-bpy complex cations in polyoxometalate chemistry.

AB - Two new Dawson-based phosphotungstates (H2en)0.5H[Cu(en)2(H2O)]2{[Cu(en)2](α1-P2W17CuO61)}·8H2O (1) (en=ethylenediamine) and [4,4′-H2bpy]2{[Cu(4,4′-bpy)3][Cu(4,4′-bpy)4(H2O)2]2[Cu(4,4′-bpy)][α-P2W18O62]2}·6H2O (2) (4,4′-bpy=4,4′-bipyridine) have been hydrothermally synthesized and structurally characterized. 1 crystallizes in the triclinic space group P-1 with a=11.7626(17), b=13.246(2), c=29.350(5) Å, α=87.355(5), β=79.583(5), γ=66.993(3)°, V=4138.3(11) Å3, Z=2, GOF=1.089, R1=0.0563 and wR2=0.1505, whereas 2 belongs to the orthorhombic space group Iba2 with a=22.277(8), b=47.04(2), c=22.153(8) Å, V=23215(17) Å3, Z=4, GOF=1.051, R1=0.0627 and wR2=0.1477. 1 consists of a 1-D linear chain structure constructed from monocopperII-substituted Dawson polyoxoanions, while 2 represents the first 2-D sheet-like structure with a (4,4)-connected topological net built up from plenary Dawson-type polyoxoanions and CuII-4,4′-bpy complex cations in polyoxometalate chemistry.

KW - Copper

KW - Dawson structure

KW - Hydrothermal reaction

KW - Polyoxometalates

UR - https://www.scopus.com/pages/publications/39649113829

U2 - 10.1016/j.jssc.2008.01.002

DO - 10.1016/j.jssc.2008.01.002

M3 - Article

AN - SCOPUS:39649113829

SN - 0022-4596

VL - 181

SP - 637

EP - 645

JO - Journal of Solid State Chemistry

JF - Journal of Solid State Chemistry

IS - 3

ER -

Hydrothermal synthesis and structural characterization of two 1-D and 2-D Dawson-based phosphotungstates

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