Hydrothermal Synthesis and Crystal Structure of a New 2-D Organic-Inorganic Hybrid Wells-Dawson-Type Polyoxometalate

Xin Xiong Li; Wei Hui Fang; Guo Yu Yang

doi:10.1007/s10876-010-0340-8

Hydrothermal Synthesis and Crystal Structure of a New 2-D Organic-Inorganic Hybrid Wells-Dawson-Type Polyoxometalate

Xin Xiong Li
, Wei Hui Fang
, Guo Yu Yang^*

^*此作品的通讯作者

CAS - Fujian Institute of Research on the Structure of Matter

科研成果: 期刊稿件 › 文章 › 同行评审

10 引用（Scopus）

摘要

A new 2-D organic-inorganic hybrid Wells-Dawson-Type polyoxotungstate K[Cu(Im)₂]₆P₂W₁₈O₆₂·2H₂O·(OH) (Im = Imidazole) (1) has been synthesized under hydrothermal conditions and characterized by IR spectroscopy, TG, and single crystal X-ray structural analysis. Crystal data for 1: triclinic, P-1, a = 15. 3676(12) Å, b = 15. 5059(14) Å, c = 24. 6437(19) Å, α = 98. 088(2)°, β = 96. 930(2)°, γ = 119. 312(2)°, Z = 2. Single crystal X-ray structural analysis reveals that the [P₂W₁₈O₆₂]^6- polyoxoanion is linked by [Cu(Im)₂]⁺ cation to form a 1-D chain along the a axis which is connected by K⁺ cation down the c axis to form a 2-D layer.

源语言	英语
页（从-至）	803-811
页数	9
期刊	Journal of Cluster Science
卷	21
期	4
DOI	https://doi.org/10.1007/s10876-010-0340-8
出版状态	已出版 - 12月 2010
已对外发布	是

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@article{3bec0bddb402468a9f30560fb8e52b7d,

title = "Hydrothermal Synthesis and Crystal Structure of a New 2-D Organic-Inorganic Hybrid Wells-Dawson-Type Polyoxometalate",

abstract = "A new 2-D organic-inorganic hybrid Wells-Dawson-Type polyoxotungstate K[Cu(Im)2]6P2W18O62·2H2O·(OH) (Im = Imidazole) (1) has been synthesized under hydrothermal conditions and characterized by IR spectroscopy, TG, and single crystal X-ray structural analysis. Crystal data for 1: triclinic, P-1, a = 15. 3676(12) {\AA}, b = 15. 5059(14) {\AA}, c = 24. 6437(19) {\AA}, α = 98. 088(2)°, β = 96. 930(2)°, γ = 119. 312(2)°, Z = 2. Single crystal X-ray structural analysis reveals that the [P2W18O62]6- polyoxoanion is linked by [Cu(Im)2]+ cation to form a 1-D chain along the a axis which is connected by K+ cation down the c axis to form a 2-D layer.",

keywords = "Copper, Crystal structure, Hydrothermal synthesis, Organic-inorganic hybrid, Polyoxometalates, Wells-Dawson",

author = "Li, \{Xin Xiong\} and Fang, \{Wei Hui\} and Yang, \{Guo Yu\}",

year = "2010",

month = dec,

doi = "10.1007/s10876-010-0340-8",

language = "English",

volume = "21",

pages = "803--811",

journal = "Journal of Cluster Science",

issn = "1040-7278",

publisher = "Springer",

number = "4",

}

TY - JOUR

T1 - Hydrothermal Synthesis and Crystal Structure of a New 2-D Organic-Inorganic Hybrid Wells-Dawson-Type Polyoxometalate

AU - Li, Xin Xiong

AU - Fang, Wei Hui

AU - Yang, Guo Yu

PY - 2010/12

Y1 - 2010/12

N2 - A new 2-D organic-inorganic hybrid Wells-Dawson-Type polyoxotungstate K[Cu(Im)2]6P2W18O62·2H2O·(OH) (Im = Imidazole) (1) has been synthesized under hydrothermal conditions and characterized by IR spectroscopy, TG, and single crystal X-ray structural analysis. Crystal data for 1: triclinic, P-1, a = 15. 3676(12) Å, b = 15. 5059(14) Å, c = 24. 6437(19) Å, α = 98. 088(2)°, β = 96. 930(2)°, γ = 119. 312(2)°, Z = 2. Single crystal X-ray structural analysis reveals that the [P2W18O62]6- polyoxoanion is linked by [Cu(Im)2]+ cation to form a 1-D chain along the a axis which is connected by K+ cation down the c axis to form a 2-D layer.

AB - A new 2-D organic-inorganic hybrid Wells-Dawson-Type polyoxotungstate K[Cu(Im)2]6P2W18O62·2H2O·(OH) (Im = Imidazole) (1) has been synthesized under hydrothermal conditions and characterized by IR spectroscopy, TG, and single crystal X-ray structural analysis. Crystal data for 1: triclinic, P-1, a = 15. 3676(12) Å, b = 15. 5059(14) Å, c = 24. 6437(19) Å, α = 98. 088(2)°, β = 96. 930(2)°, γ = 119. 312(2)°, Z = 2. Single crystal X-ray structural analysis reveals that the [P2W18O62]6- polyoxoanion is linked by [Cu(Im)2]+ cation to form a 1-D chain along the a axis which is connected by K+ cation down the c axis to form a 2-D layer.

KW - Copper

KW - Crystal structure

KW - Hydrothermal synthesis

KW - Organic-inorganic hybrid

KW - Polyoxometalates

KW - Wells-Dawson

UR - https://www.scopus.com/pages/publications/78650186574

U2 - 10.1007/s10876-010-0340-8

DO - 10.1007/s10876-010-0340-8

M3 - Article

AN - SCOPUS:78650186574

SN - 1040-7278

VL - 21

SP - 803

EP - 811

JO - Journal of Cluster Science

JF - Journal of Cluster Science

IS - 4

ER -

Hydrothermal Synthesis and Crystal Structure of a New 2-D Organic-Inorganic Hybrid Wells-Dawson-Type Polyoxometalate

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