Hydrogenation of SBS catalyzed by immobilized Ru-TPPTS complex in polyether molten salt

Li Wei; Jing Yang Jiang; Yan Hua Wang; Zi Lin Jin

Hydrogenation of SBS catalyzed by immobilized Ru-TPPTS complex in polyether molten salt

Li Wei^*
, Jing Yang Jiang
, Yan Hua Wang
, Zi Lin Jin

^*此作品的通讯作者

Dalian University of Technology

科研成果: 期刊稿件 › 文章 › 同行评审

2 引用（Scopus）

摘要

Catalytic hydrogenation of SBS was performed for the first time in polyether molten salt with Ru/TPPTS complex as catalyst. Experimental results showed that the hydrogenation degree can be enhanced significantly by the addition of triphenylphosphine (TPP). When the molar ratio of TPP, TPPTS and Ru is 2:5:1. 89% hydrogenation degree can be achieved after 12 h under reaction conditions of 5.0 MPa and 150°C. The ionic liquid containing catalyst can be reused three times without obvious changes in the catalytic selectivity and activity.

源语言	英语
页（从-至）	338-340
页数	3
期刊	Chinese Chemical Letters
卷	16
期	3
出版状态	已出版 - 3月 2005
已对外发布	是

其它文件与链接

链接到 Scopus 的出版物

引用此

@article{21208ab044ac4b7f8ba73585d8867eb1,

title = "Hydrogenation of SBS catalyzed by immobilized Ru-TPPTS complex in polyether molten salt",

abstract = "Catalytic hydrogenation of SBS was performed for the first time in polyether molten salt with Ru/TPPTS complex as catalyst. Experimental results showed that the hydrogenation degree can be enhanced significantly by the addition of triphenylphosphine (TPP). When the molar ratio of TPP, TPPTS and Ru is 2:5:1. 89\% hydrogenation degree can be achieved after 12 h under reaction conditions of 5.0 MPa and 150°C. The ionic liquid containing catalyst can be reused three times without obvious changes in the catalytic selectivity and activity.",

keywords = "Hydrogenation, Polyether molten salt, Ruthenium complex, SBS",

author = "Li Wei and Jiang, \{Jing Yang\} and Wang, \{Yan Hua\} and Jin, \{Zi Lin\}",

year = "2005",

month = mar,

language = "English",

volume = "16",

pages = "338--340",

journal = "Chinese Chemical Letters",

issn = "1001-8417",

publisher = "Elsevier B.V.",

number = "3",

}

TY - JOUR

T1 - Hydrogenation of SBS catalyzed by immobilized Ru-TPPTS complex in polyether molten salt

AU - Wei, Li

AU - Jiang, Jing Yang

AU - Wang, Yan Hua

AU - Jin, Zi Lin

PY - 2005/3

Y1 - 2005/3

N2 - Catalytic hydrogenation of SBS was performed for the first time in polyether molten salt with Ru/TPPTS complex as catalyst. Experimental results showed that the hydrogenation degree can be enhanced significantly by the addition of triphenylphosphine (TPP). When the molar ratio of TPP, TPPTS and Ru is 2:5:1. 89% hydrogenation degree can be achieved after 12 h under reaction conditions of 5.0 MPa and 150°C. The ionic liquid containing catalyst can be reused three times without obvious changes in the catalytic selectivity and activity.

AB - Catalytic hydrogenation of SBS was performed for the first time in polyether molten salt with Ru/TPPTS complex as catalyst. Experimental results showed that the hydrogenation degree can be enhanced significantly by the addition of triphenylphosphine (TPP). When the molar ratio of TPP, TPPTS and Ru is 2:5:1. 89% hydrogenation degree can be achieved after 12 h under reaction conditions of 5.0 MPa and 150°C. The ionic liquid containing catalyst can be reused three times without obvious changes in the catalytic selectivity and activity.

KW - Hydrogenation

KW - Polyether molten salt

KW - Ruthenium complex

KW - SBS

UR - https://www.scopus.com/pages/publications/33745027191

M3 - Article

AN - SCOPUS:33745027191

SN - 1001-8417

VL - 16

SP - 338

EP - 340

JO - Chinese Chemical Letters

JF - Chinese Chemical Letters

IS - 3

ER -

Hydrogenation of SBS catalyzed by immobilized Ru-TPPTS complex in polyether molten salt

摘要

其它文件与链接

指纹

引用此