Highly compressible and anisotropic lamellar ceramic sponges with superior thermal insulation and acoustic absorption performances

Advanced ceramic sponge materials with temperature-invariant high compressibility are urgently needed as thermal insulators, energy absorbers, catalyst carriers, and high temperature air filters. However, the application of ceramic sponge materials is severely limited due to their complex preparation process. Here, we present a facile method for large-scale fabrication of highly compressible, temperature resistant SiO₂-Al₂O₃ composite ceramic sponges by blow spinning and subsequent calcination. We successfully produce anisotropic lamellar ceramic sponges with numerous stacked microfiber layers and density as low as 10 mg cm⁻³. The anisotropic lamellar ceramic sponges exhibit high compression fatigue resistance, strain-independent zero Poisson’s ratio, robust fire resistance, temperature-invariant compression resilience from −196 to 1000 °C, and excellent thermal insulation with a thermal conductivity as low as 0.034 W m⁻¹ K⁻¹. In addition, the lamellar structure also endows the ceramic sponges with excellent sound absorption properties, representing a promising alternative to existing thermal insulation and acoustic absorption materials.