Hexa-substituted polyoxometalates made of trivacant Dawson {P 2W15} fragments and {Ni6} clusters under hydrothermal conditions

Yong Chao Liu; Chun Hua Fu; Shou Tian Zheng; Jun Wei Zhao; Guo Yu Yang

doi:10.1039/c3dt51786a

Hexa-substituted polyoxometalates made of trivacant Dawson {P ₂W₁₅} fragments and {Ni₆} clusters under hydrothermal conditions

Yong Chao Liu
, Chun Hua Fu
, Shou Tian Zheng
, Jun Wei Zhao^*
, Guo Yu Yang

^*此作品的通讯作者

CAS - Fujian Institute of Research on the Structure of Matter
Henan University

科研成果: 期刊稿件 › 文章 › 同行评审

23 引用（Scopus）

摘要

Three novel polyoxometalates (POMs) containing [Ni₆(μ ₃-OH)₃]^9- and [P₂W ₁₅O₅₆]^12- units were first made, showing the first hexa-nuclearity transition-metal substituted POMs (TMSPs) based on monomeric lacunary Dawson fragments, which further indicates that the hydrothermal technique can offer an effective way for making new TMSPs through lacunary POM fragments incorporated with high-nuclear TM clusters.

源语言	英语
页（从-至）	16676-16679
页数	4
期刊	Dalton Transactions
卷	42
期	48
DOI	https://doi.org/10.1039/c3dt51786a
出版状态	已出版 - 28 12月 2013
已对外发布	是

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10.1039/c3dt51786a

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title = "Hexa-substituted polyoxometalates made of trivacant Dawson \{P 2W15\} fragments and \{Ni6\} clusters under hydrothermal conditions",

abstract = "Three novel polyoxometalates (POMs) containing [Ni6(μ 3-OH)3]9- and [P2W 15O56]12- units were first made, showing the first hexa-nuclearity transition-metal substituted POMs (TMSPs) based on monomeric lacunary Dawson fragments, which further indicates that the hydrothermal technique can offer an effective way for making new TMSPs through lacunary POM fragments incorporated with high-nuclear TM clusters.",

author = "Liu, \{Yong Chao\} and Fu, \{Chun Hua\} and Zheng, \{Shou Tian\} and Zhao, \{Jun Wei\} and Yang, \{Guo Yu\}",

year = "2013",

month = dec,

day = "28",

doi = "10.1039/c3dt51786a",

language = "English",

volume = "42",

pages = "16676--16679",

journal = "Dalton Transactions",

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T1 - Hexa-substituted polyoxometalates made of trivacant Dawson {P 2W15} fragments and {Ni6} clusters under hydrothermal conditions

AU - Liu, Yong Chao

AU - Fu, Chun Hua

AU - Zheng, Shou Tian

AU - Zhao, Jun Wei

AU - Yang, Guo Yu

PY - 2013/12/28

Y1 - 2013/12/28

N2 - Three novel polyoxometalates (POMs) containing [Ni6(μ 3-OH)3]9- and [P2W 15O56]12- units were first made, showing the first hexa-nuclearity transition-metal substituted POMs (TMSPs) based on monomeric lacunary Dawson fragments, which further indicates that the hydrothermal technique can offer an effective way for making new TMSPs through lacunary POM fragments incorporated with high-nuclear TM clusters.

AB - Three novel polyoxometalates (POMs) containing [Ni6(μ 3-OH)3]9- and [P2W 15O56]12- units were first made, showing the first hexa-nuclearity transition-metal substituted POMs (TMSPs) based on monomeric lacunary Dawson fragments, which further indicates that the hydrothermal technique can offer an effective way for making new TMSPs through lacunary POM fragments incorporated with high-nuclear TM clusters.

UR - https://www.scopus.com/pages/publications/84888254135

U2 - 10.1039/c3dt51786a

DO - 10.1039/c3dt51786a

M3 - Article

AN - SCOPUS:84888254135

SN - 1477-9226

VL - 42

SP - 16676

EP - 16679

JO - Dalton Transactions

JF - Dalton Transactions

IS - 48

ER -

Hexa-substituted polyoxometalates made of trivacant Dawson {P 2W15} fragments and {Ni6} clusters under hydrothermal conditions

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Hexa-substituted polyoxometalates made of trivacant Dawson {P ₂W₁₅} fragments and {Ni₆} clusters under hydrothermal conditions