Heterostructured CoS₂/CuCo₂S₄@N-doped carbon hollow sphere for potassium-ion batteries

Potassium ions batteries (PIBs) have been regarded as a promising choice for electrical energy storage technology due to the wide distribution of potassium resources. However, developing low-cost and robust earth-rich anode materials is still a major challenge for the practical and scalable usage of PIBs. Herein, for the first time, we developed nitrogen doped carbon coating CoS₂/CuCo₂S₄ heterostructure (CoS₂/CuCo₂S₄@NCs) hollow spheres and evaluated as anode for PIBs. The CoS₂ and CuCo₂S₄ heterostructure interface could generate a built-in electric field, which can fasten electrons transportation. The nanostructures could shorten the diffusion length of K⁺ and provide large surface area to contact with electrolytes. Furthermore, the inner hollow sphere morphology along with the carbon layer could accommodate the volume expansion during cycling. What's more, the N-doped carbon could increase the conductivity of the anodes. Benefitting from the above features, the CoS₂/CuCo₂S₄@NCs displays an outstanding rate capability (309 mAh g⁻¹ at 500 mA g⁻¹ after 250 cycles) and a long-term cycling life (112 mAh g⁻¹ at 1000 mA g⁻¹ after 1000 cycles) in ether-based electrolyte. Conversion reaction mechanism in CoS₂/CuCo₂S₄@NCs anode is also revealed through ex situ XRD characterizations. This work provides a practical direction for investigating metal sulfides as anode for PIBs.