TY - JOUR
T1 - Fused triazolotriazine bearing a
T2 - Gem -dinitro group: A promising high energy density material
AU - Wang, Shaoqing
AU - Li, Congcong
AU - Lu, Tian
AU - Wang, Guilong
AU - Yin, Hongquan
AU - Ma, Qing
AU - Fan, Guijuan
AU - Chen, Fuxue
N1 - Publisher Copyright:
© 2021 The Royal Society of Chemistry and the Centre National de la Recherche Scientifique.
PY - 2021/6/14
Y1 - 2021/6/14
N2 - Six energetic compounds bearing the dinitromethyl group and based on the triazolotriazine fused ring skeleton were achieved. All structures were confirmed using infrared spectroscopy (IR), 1H NMR and 13C NMR spectroscopy, high-resolution mass spectrometry (HRMS) and differential scanning calorimetry (DSC). Among them, potassium salt and neutral compound 3,7-bis(fluorodinitromethyl)-[1,2,4]triazolo[5,1-c][1,2,4]triazin-4-amine exhibit high densities (2.06 g cm-3 and 1.95 g cm-3, respectively), detonation velocities of up to 9028 m s-1, and excellent friction sensitivity (>360 N).
AB - Six energetic compounds bearing the dinitromethyl group and based on the triazolotriazine fused ring skeleton were achieved. All structures were confirmed using infrared spectroscopy (IR), 1H NMR and 13C NMR spectroscopy, high-resolution mass spectrometry (HRMS) and differential scanning calorimetry (DSC). Among them, potassium salt and neutral compound 3,7-bis(fluorodinitromethyl)-[1,2,4]triazolo[5,1-c][1,2,4]triazin-4-amine exhibit high densities (2.06 g cm-3 and 1.95 g cm-3, respectively), detonation velocities of up to 9028 m s-1, and excellent friction sensitivity (>360 N).
UR - https://www.scopus.com/pages/publications/85107703832
U2 - 10.1039/d1nj01051d
DO - 10.1039/d1nj01051d
M3 - Article
AN - SCOPUS:85107703832
SN - 1144-0546
VL - 45
SP - 9766
EP - 9769
JO - New Journal of Chemistry
JF - New Journal of Chemistry
IS - 22
ER -