Fused Triazole-Tetrazine Assembled with Different Functional Moieties: Construction of Multipurpose Energetic Materials

Hui Zhang; Xinyu Du; Yongjiang Liu; Guorong Lei; Ping Yin; Siping Pang

doi:10.1021/acsomega.4c01261

Fused Triazole-Tetrazine Assembled with Different Functional Moieties: Construction of Multipurpose Energetic Materials

Hui Zhang
, Xinyu Du
, Yongjiang Liu^*
, Guorong Lei
, Ping Yin^*
, Siping Pang

^*此作品的通讯作者

材料学院

Beijing Institute of Technology

科研成果: 期刊稿件 › 文章 › 同行评审

8 引用（Scopus）

摘要

Azido, amino, and azo functionalities were introduced into tetrazine backbones to access multifunctional energetic materials. AzNTT demonstrates effective initiation capability (MPC = 50 mg), whereas NTTA balances well between the energy and stability. Azo-functionalized BNTTD has a high density of 1.908 g cm^-3, with performance comparable to that of the benchmark material HMX. This work underscores the scope of energetic functionalization and the outstanding comprehensive performance of polycyclic tetrazines.

源语言	英语
页（从-至）	33557-33562
页数	6
期刊	ACS Omega
卷	9
期	31
DOI	https://doi.org/10.1021/acsomega.4c01261
出版状态	已出版 - 6 8月 2024

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10.1021/acsomega.4c01261

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abstract = "Azido, amino, and azo functionalities were introduced into tetrazine backbones to access multifunctional energetic materials. AzNTT demonstrates effective initiation capability (MPC = 50 mg), whereas NTTA balances well between the energy and stability. Azo-functionalized BNTTD has a high density of 1.908 g cm-3, with performance comparable to that of the benchmark material HMX. This work underscores the scope of energetic functionalization and the outstanding comprehensive performance of polycyclic tetrazines.",

author = "Hui Zhang and Xinyu Du and Yongjiang Liu and Guorong Lei and Ping Yin and Siping Pang",

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T2 - Construction of Multipurpose Energetic Materials

AU - Zhang, Hui

AU - Du, Xinyu

AU - Liu, Yongjiang

AU - Lei, Guorong

AU - Yin, Ping

AU - Pang, Siping

PY - 2024/8/6

Y1 - 2024/8/6

N2 - Azido, amino, and azo functionalities were introduced into tetrazine backbones to access multifunctional energetic materials. AzNTT demonstrates effective initiation capability (MPC = 50 mg), whereas NTTA balances well between the energy and stability. Azo-functionalized BNTTD has a high density of 1.908 g cm-3, with performance comparable to that of the benchmark material HMX. This work underscores the scope of energetic functionalization and the outstanding comprehensive performance of polycyclic tetrazines.

AB - Azido, amino, and azo functionalities were introduced into tetrazine backbones to access multifunctional energetic materials. AzNTT demonstrates effective initiation capability (MPC = 50 mg), whereas NTTA balances well between the energy and stability. Azo-functionalized BNTTD has a high density of 1.908 g cm-3, with performance comparable to that of the benchmark material HMX. This work underscores the scope of energetic functionalization and the outstanding comprehensive performance of polycyclic tetrazines.

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Fused Triazole-Tetrazine Assembled with Different Functional Moieties: Construction of Multipurpose Energetic Materials

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