Four coordination polymers based on identical eight-connected heptanuclear clusters: Spin canting, spin glass, antiferromagnetism, and gas adsorption

Jia Li; Bao Li; Peng Huang; Hai Yan Shi; Rong Bin Huang; Lan Sun Zheng; Jun Tao

doi:10.1021/ic401912k

Four coordination polymers based on identical eight-connected heptanuclear clusters: Spin canting, spin glass, antiferromagnetism, and gas adsorption

Jia Li
, Bao Li
, Peng Huang
, Hai Yan Shi^*
, Rong Bin Huang
, Lan Sun Zheng
, Jun Tao

^*此作品的通讯作者

Xiamen University
Huazhong University of Science and Technology

科研成果: 期刊稿件 › 文章 › 同行评审

45 引用（Scopus）

摘要

Four 3D coordination polymers, [Co₇(OH)₄(H ₂O)₂(ina)₄(ip)₃]·10H ₂O (1·10H₂O, ina = isonicotinate, ip = isophthalate), [Ni₇(OH)₄(H₂O) ₂(ina)₄(ip)₃]·10H₂O (2·10H₂O), [Co₇(OH)₄(H ₂O)₂(ina)₄(pip)₃]·5H ₂O (3·5H₂O, pip = 5-phenyl-isophthalate), and [Ni₇(OH)₄(H₂O)₂(ina) ₄(pip)₃]·5H₂O (4·5H ₂O), respectively, were hydrothermally synthesized. They crystallized in the orthorhombic space group Pba2 for 1·10H₂O and 2·10H₂O and monoclinic space group P2/n for 3·5H ₂O and 4·5H₂O, respectively, and were constructed with the identical 8-connected heptanuclear {M₇(OH)₄} (M = Co^II or Ni^II) clusters, possessing uninodal hexagonal primitive net with the point symbol {3⁶·4¹⁸· 5³·6}. The four coordination polymers showed dominant antiferromangetic properties, in which 1·10H₂O shows spin-canted behavior and 2·10H₂O exhibits the coexistence of spin canting and spin glass. Meanwhile, the activated polymers 1 and 2 possessed permanent porosity, displaying relatively large H₂ uptake capacity (77 K, 1 atm) of 114 and 133 cm³ g^-1, and CO₂ uptake capacity (273 K, 1 atm) of 65.8 and 73.3 cm³ g^-1, for 1 and 2, respectively.

源语言	英语
页（从-至）	11573-11579
页数	7
期刊	Inorganic Chemistry
卷	52
期	19
DOI	https://doi.org/10.1021/ic401912k
出版状态	已出版 - 7 10月 2013
已对外发布	是

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@article{2c6a1af1eac446479f7f6ba3da29c932,

title = "Four coordination polymers based on identical eight-connected heptanuclear clusters: Spin canting, spin glass, antiferromagnetism, and gas adsorption",

abstract = "Four 3D coordination polymers, [Co7(OH)4(H 2O)2(ina)4(ip)3]·10H 2O (1·10H2O, ina = isonicotinate, ip = isophthalate), [Ni7(OH)4(H2O) 2(ina)4(ip)3]·10H2O (2·10H2O), [Co7(OH)4(H 2O)2(ina)4(pip)3]·5H 2O (3·5H2O, pip = 5-phenyl-isophthalate), and [Ni7(OH)4(H2O)2(ina) 4(pip)3]·5H2O (4·5H 2O), respectively, were hydrothermally synthesized. They crystallized in the orthorhombic space group Pba2 for 1·10H2O and 2·10H2O and monoclinic space group P2/n for 3·5H 2O and 4·5H2O, respectively, and were constructed with the identical 8-connected heptanuclear \{M7(OH)4\} (M = CoII or NiII) clusters, possessing uninodal hexagonal primitive net with the point symbol \{36·418· 53·6\}. The four coordination polymers showed dominant antiferromangetic properties, in which 1·10H2O shows spin-canted behavior and 2·10H2O exhibits the coexistence of spin canting and spin glass. Meanwhile, the activated polymers 1 and 2 possessed permanent porosity, displaying relatively large H2 uptake capacity (77 K, 1 atm) of 114 and 133 cm3 g-1, and CO2 uptake capacity (273 K, 1 atm) of 65.8 and 73.3 cm3 g-1, for 1 and 2, respectively.",

author = "Jia Li and Bao Li and Peng Huang and Shi, \{Hai Yan\} and Huang, \{Rong Bin\} and Zheng, \{Lan Sun\} and Jun Tao",

year = "2013",

month = oct,

day = "7",

doi = "10.1021/ic401912k",

language = "English",

volume = "52",

pages = "11573--11579",

journal = "Inorganic Chemistry",

issn = "0020-1669",

publisher = "American Chemical Society",

number = "19",

}

TY - JOUR

T1 - Four coordination polymers based on identical eight-connected heptanuclear clusters

T2 - Spin canting, spin glass, antiferromagnetism, and gas adsorption

AU - Li, Jia

AU - Li, Bao

AU - Huang, Peng

AU - Shi, Hai Yan

AU - Huang, Rong Bin

AU - Zheng, Lan Sun

AU - Tao, Jun

PY - 2013/10/7

Y1 - 2013/10/7

N2 - Four 3D coordination polymers, [Co7(OH)4(H 2O)2(ina)4(ip)3]·10H 2O (1·10H2O, ina = isonicotinate, ip = isophthalate), [Ni7(OH)4(H2O) 2(ina)4(ip)3]·10H2O (2·10H2O), [Co7(OH)4(H 2O)2(ina)4(pip)3]·5H 2O (3·5H2O, pip = 5-phenyl-isophthalate), and [Ni7(OH)4(H2O)2(ina) 4(pip)3]·5H2O (4·5H 2O), respectively, were hydrothermally synthesized. They crystallized in the orthorhombic space group Pba2 for 1·10H2O and 2·10H2O and monoclinic space group P2/n for 3·5H 2O and 4·5H2O, respectively, and were constructed with the identical 8-connected heptanuclear {M7(OH)4} (M = CoII or NiII) clusters, possessing uninodal hexagonal primitive net with the point symbol {36·418· 53·6}. The four coordination polymers showed dominant antiferromangetic properties, in which 1·10H2O shows spin-canted behavior and 2·10H2O exhibits the coexistence of spin canting and spin glass. Meanwhile, the activated polymers 1 and 2 possessed permanent porosity, displaying relatively large H2 uptake capacity (77 K, 1 atm) of 114 and 133 cm3 g-1, and CO2 uptake capacity (273 K, 1 atm) of 65.8 and 73.3 cm3 g-1, for 1 and 2, respectively.

AB - Four 3D coordination polymers, [Co7(OH)4(H 2O)2(ina)4(ip)3]·10H 2O (1·10H2O, ina = isonicotinate, ip = isophthalate), [Ni7(OH)4(H2O) 2(ina)4(ip)3]·10H2O (2·10H2O), [Co7(OH)4(H 2O)2(ina)4(pip)3]·5H 2O (3·5H2O, pip = 5-phenyl-isophthalate), and [Ni7(OH)4(H2O)2(ina) 4(pip)3]·5H2O (4·5H 2O), respectively, were hydrothermally synthesized. They crystallized in the orthorhombic space group Pba2 for 1·10H2O and 2·10H2O and monoclinic space group P2/n for 3·5H 2O and 4·5H2O, respectively, and were constructed with the identical 8-connected heptanuclear {M7(OH)4} (M = CoII or NiII) clusters, possessing uninodal hexagonal primitive net with the point symbol {36·418· 53·6}. The four coordination polymers showed dominant antiferromangetic properties, in which 1·10H2O shows spin-canted behavior and 2·10H2O exhibits the coexistence of spin canting and spin glass. Meanwhile, the activated polymers 1 and 2 possessed permanent porosity, displaying relatively large H2 uptake capacity (77 K, 1 atm) of 114 and 133 cm3 g-1, and CO2 uptake capacity (273 K, 1 atm) of 65.8 and 73.3 cm3 g-1, for 1 and 2, respectively.

UR - https://www.scopus.com/pages/publications/84885168023

U2 - 10.1021/ic401912k

DO - 10.1021/ic401912k

M3 - Article

AN - SCOPUS:84885168023

SN - 0020-1669

VL - 52

SP - 11573

EP - 11579

JO - Inorganic Chemistry

JF - Inorganic Chemistry

IS - 19

ER -

Four coordination polymers based on identical eight-connected heptanuclear clusters: Spin canting, spin glass, antiferromagnetism, and gas adsorption

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