TY - JOUR
T1 - Formyl azido substituted nitro hexaazaisowurtzitane-synthesis, characterization and energetic properties
AU - Dong, Kai
AU - Wang, Yuan
AU - Gong, Xu Bin
AU - Zhang, Jing
AU - Sun, Cheng Hui
AU - Pang, Si Ping
PY - 2013/11
Y1 - 2013/11
N2 - Formyl azido substituted nitro hexaazaisowurtzitane derivatives, 2,4,6,8,12-pentanitro-10-formylazido-hexaazaisowurtzitane and 2,6,8,12-tetranitro-4,10-diformylazido-hexaazaisowurtzitane, have been synthesized and well characterized by IR and NMR (1H, 13C) spectroscopy, mass spectroscopy (MS), differential scanning calorimetry (DSC), thermogravimetric analysis (TGA) and single-crystal X-ray diffraction. Their key properties such as melting points and decomposition temperatures, densities, dissociation energy of bonds (BDE), electrostatic potential (ESP), impact sensitivity (IS), detonation pressures (P) and velocities (D) were measured or calculated, which indicated an excellent combination of admirable detonation performance and stability as potential energetic compounds.
AB - Formyl azido substituted nitro hexaazaisowurtzitane derivatives, 2,4,6,8,12-pentanitro-10-formylazido-hexaazaisowurtzitane and 2,6,8,12-tetranitro-4,10-diformylazido-hexaazaisowurtzitane, have been synthesized and well characterized by IR and NMR (1H, 13C) spectroscopy, mass spectroscopy (MS), differential scanning calorimetry (DSC), thermogravimetric analysis (TGA) and single-crystal X-ray diffraction. Their key properties such as melting points and decomposition temperatures, densities, dissociation energy of bonds (BDE), electrostatic potential (ESP), impact sensitivity (IS), detonation pressures (P) and velocities (D) were measured or calculated, which indicated an excellent combination of admirable detonation performance and stability as potential energetic compounds.
UR - http://www.scopus.com/inward/record.url?scp=84885742534&partnerID=8YFLogxK
U2 - 10.1039/c3nj00532a
DO - 10.1039/c3nj00532a
M3 - Article
AN - SCOPUS:84885742534
SN - 1144-0546
VL - 37
SP - 3685
EP - 3691
JO - New Journal of Chemistry
JF - New Journal of Chemistry
IS - 11
ER -