TY - JOUR
T1 - Fluorination of etheric substrates adsorbed on porous aluminium fluoride by gaseous fluorine
AU - Quan, Heng Dao
AU - Tamura, Masanori
AU - Murata, Junji
AU - Gao, Ren Xiao
AU - Sekiya, Akira
PY - 2000/12
Y1 - 2000/12
N2 - A novel fluorination procedure of etheric substrates adsorbed on porous aluminium fluoride (PAF) using gaseous fluorine has been investigated. The reaction of ethyl 1,1,2,2-tetrafluoroethylether 1 and 2-chloro-1,1,2-trifluoroethylmethylether 9 with fluorine proceeds with upto 58% selectivity for α-monofluorinated 1 and 96% selectivity for α-monofluorinated 9. At the same time, charring can be avoided in the fluorination process.
AB - A novel fluorination procedure of etheric substrates adsorbed on porous aluminium fluoride (PAF) using gaseous fluorine has been investigated. The reaction of ethyl 1,1,2,2-tetrafluoroethylether 1 and 2-chloro-1,1,2-trifluoroethylmethylether 9 with fluorine proceeds with upto 58% selectivity for α-monofluorinated 1 and 96% selectivity for α-monofluorinated 9. At the same time, charring can be avoided in the fluorination process.
KW - 2-chloro-1,1,2-trifluoroethylmethylether
KW - Ethyl 1,1,2,2-tetrafluoroethylether
KW - Fluorination
KW - Porous aluminium fluoride
UR - https://www.scopus.com/pages/publications/0000223052
U2 - 10.1016/S0022-1139(00)00317-1
DO - 10.1016/S0022-1139(00)00317-1
M3 - Article
AN - SCOPUS:0000223052
SN - 0022-1139
VL - 106
SP - 121
EP - 125
JO - Journal of Fluorine Chemistry
JF - Journal of Fluorine Chemistry
IS - 2
ER -