TY - JOUR
T1 - Fluorination of chlorofluoroether using catalysts supported by porous aluminum fluoride
AU - Sekiya, Akira
AU - Quan, Heng Dao
AU - Tamura, Masanori
AU - Gao, Ren Xiao
AU - Murata, Junji
PY - 2001
Y1 - 2001
N2 - Reaction of 1,2-dichloro-1,1,2-trifluoro-2-methoxyethane with anhydrous hydrogen fluoride (AHF) was investigated in the presence of metal fluorides supported on porous aluminum fluoride (PAF). 2-Chloro-1,1,2,2-tetrafluoro-2-methoxyethane, a new compound, was prepared in 85% yield in the presence of CoF2/PAF. Methyl chlorodifluoroacetate was also obtained and its formation was discussed.
AB - Reaction of 1,2-dichloro-1,1,2-trifluoro-2-methoxyethane with anhydrous hydrogen fluoride (AHF) was investigated in the presence of metal fluorides supported on porous aluminum fluoride (PAF). 2-Chloro-1,1,2,2-tetrafluoro-2-methoxyethane, a new compound, was prepared in 85% yield in the presence of CoF2/PAF. Methyl chlorodifluoroacetate was also obtained and its formation was discussed.
KW - 1,2-Dichloro-1,1,2-trifluoro-2-methoxyethane
KW - 2-Chloro-1,1,2, 2-tetrafluoro-2-methoxyethane
KW - Methyl chlorodifluoroacetate
KW - Porous aluminum fluoride
UR - https://www.scopus.com/pages/publications/0035160368
U2 - 10.1016/S0022-1139(01)00483-3
DO - 10.1016/S0022-1139(01)00483-3
M3 - Article
AN - SCOPUS:0035160368
SN - 0022-1139
VL - 112
SP - 145
EP - 148
JO - Journal of Fluorine Chemistry
JF - Journal of Fluorine Chemistry
IS - 1
ER -