TY - JOUR
T1 - Flash pyrolysis of trinitrophloroglucinol metallic (Li, Na, K, Mg) compounds
AU - Zhang, Qiang
AU - Qiao, Xiao Jing
AU - Zhang, Jian Guo
AU - Zuo, Xiao Li
PY - 2009/6
Y1 - 2009/6
N2 - The T-jump/FTIR (Fourier transform infrared) spectroscopy technique was used to study the flash pyrolysis of metallic (Li, Na, K, Mg) compounds of trinitrophloroglucinol (TNPG, 2,4,6-trinitro-1,3,5-trihydroxybenzene). Volatile metallic compounds liberated during the flash pyrolysis of trinitrophloroglucinol metallic (Li, Na, K, Mg) compounds were determined. A curve showing the concentration of gas with time during flash pyrolysis was also derived. A qualitative and quantitative analysis of the main IR-active gas products resulted from the thermal decomposition was carried out. The REAL program was used to study the components of the combustion products, reaction thermodynamics and the burning temperature of trinitrophloroglucinol metallic (Li, Na, K, Mg) compounds, which were compared with experimental results gained from the T-jump/FTIR spectroscopy technique.
AB - The T-jump/FTIR (Fourier transform infrared) spectroscopy technique was used to study the flash pyrolysis of metallic (Li, Na, K, Mg) compounds of trinitrophloroglucinol (TNPG, 2,4,6-trinitro-1,3,5-trihydroxybenzene). Volatile metallic compounds liberated during the flash pyrolysis of trinitrophloroglucinol metallic (Li, Na, K, Mg) compounds were determined. A curve showing the concentration of gas with time during flash pyrolysis was also derived. A qualitative and quantitative analysis of the main IR-active gas products resulted from the thermal decomposition was carried out. The REAL program was used to study the components of the combustion products, reaction thermodynamics and the burning temperature of trinitrophloroglucinol metallic (Li, Na, K, Mg) compounds, which were compared with experimental results gained from the T-jump/FTIR spectroscopy technique.
KW - Flash pyrolysis
KW - REAL program
KW - T-jump/FTIR spectroscopy
KW - Trinitrophloroglucinol compound
UR - https://www.scopus.com/pages/publications/67650935423
U2 - 10.3866/pku.whxb20090622
DO - 10.3866/pku.whxb20090622
M3 - Article
AN - SCOPUS:67650935423
SN - 1000-6818
VL - 25
SP - 1081
EP - 1087
JO - Wuli Huaxue Xuebao/ Acta Physico - Chimica Sinica
JF - Wuli Huaxue Xuebao/ Acta Physico - Chimica Sinica
IS - 6
ER -