Enantioselective Selenol-ene Using Rh-Hydride Catalysis

Hannah S. Slocumb; Shaozhen Nie; Vy M. Dong; Xiao Hui Yang

doi:10.1021/jacs.2c08475

Enantioselective Selenol-ene Using Rh-Hydride Catalysis

Hannah S. Slocumb
, Shaozhen Nie
, Vy M. Dong^*
, Xiao Hui Yang^*

^*此作品的通讯作者

University of California at Irvine
Beijing Institute of Technology

科研成果: 期刊稿件 › 文章 › 同行评审

40 引用（Scopus）

摘要

This study showcases the first enantioselective hydroselenation of styrenes. Organoselenium building blocks are accessed with selectivity for the branched isomer. Through a Rh-hydride pathway, C-Se bonds can be forged with excellent regio- and enantiocontrol.

源语言	英语
页（从-至）	18246-18250
页数	5
期刊	Journal of the American Chemical Society
卷	144
期	40
DOI	https://doi.org/10.1021/jacs.2c08475
出版状态	已出版 - 12 10月 2022
已对外发布	是

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10.1021/jacs.2c08475

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title = "Enantioselective Selenol-ene Using Rh-Hydride Catalysis",

abstract = "This study showcases the first enantioselective hydroselenation of styrenes. Organoselenium building blocks are accessed with selectivity for the branched isomer. Through a Rh-hydride pathway, C-Se bonds can be forged with excellent regio- and enantiocontrol.",

author = "Slocumb, \{Hannah S.\} and Shaozhen Nie and Dong, \{Vy M.\} and Yang, \{Xiao Hui\}",

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AU - Slocumb, Hannah S.

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AU - Dong, Vy M.

AU - Yang, Xiao Hui

PY - 2022/10/12

Y1 - 2022/10/12

N2 - This study showcases the first enantioselective hydroselenation of styrenes. Organoselenium building blocks are accessed with selectivity for the branched isomer. Through a Rh-hydride pathway, C-Se bonds can be forged with excellent regio- and enantiocontrol.

AB - This study showcases the first enantioselective hydroselenation of styrenes. Organoselenium building blocks are accessed with selectivity for the branched isomer. Through a Rh-hydride pathway, C-Se bonds can be forged with excellent regio- and enantiocontrol.

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U2 - 10.1021/jacs.2c08475

DO - 10.1021/jacs.2c08475

M3 - Article

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EP - 18250

JO - Journal of the American Chemical Society

JF - Journal of the American Chemical Society

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Enantioselective Selenol-ene Using Rh-Hydride Catalysis

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