Effect of chelate size of bisoxazolines on the enantioselectivity of the asymmetric aziridination

Lin Ge Ma; Da Ming Du; Jia Xi Xu

Effect of chelate size of bisoxazolines on the enantioselectivity of the asymmetric aziridination

Lin Ge Ma^*
, Da Ming Du
, Jia Xi Xu

^*此作品的通讯作者

Peking University

科研成果: 期刊稿件 › 文章 › 同行评审

2 引用（Scopus）

摘要

Chiral bisoxazolines have been widely applied ligands to asymmetric catalysis and a series of optically active bisoxazolines with rigid backbones and different chelate sizes were synthesized. The effect of their chelate sizes on the enantioselectivity was investigated in the asymmetric aziridination. The results indicate that tuning chelate size can not only change the enantioselectivity, but also change the enantiofacial selectivity completely.

源语言	英语
页（从-至）	568-572
页数	5
期刊	Chinese Journal of Organic Chemistry
卷	26
期	4
出版状态	已出版 - 4月 2006
已对外发布	是

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title = "Effect of chelate size of bisoxazolines on the enantioselectivity of the asymmetric aziridination",

abstract = "Chiral bisoxazolines have been widely applied ligands to asymmetric catalysis and a series of optically active bisoxazolines with rigid backbones and different chelate sizes were synthesized. The effect of their chelate sizes on the enantioselectivity was investigated in the asymmetric aziridination. The results indicate that tuning chelate size can not only change the enantioselectivity, but also change the enantiofacial selectivity completely.",

keywords = "Asymmetric aziridination, Bisoxazoline, Chelate size, Enantioselectivity, Ligand",

author = "Ma, \{Lin Ge\} and Du, \{Da Ming\} and Xu, \{Jia Xi\}",

year = "2006",

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language = "English",

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pages = "568--572",

journal = "Chinese Journal of Organic Chemistry",

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T1 - Effect of chelate size of bisoxazolines on the enantioselectivity of the asymmetric aziridination

AU - Ma, Lin Ge

AU - Du, Da Ming

AU - Xu, Jia Xi

PY - 2006/4

Y1 - 2006/4

N2 - Chiral bisoxazolines have been widely applied ligands to asymmetric catalysis and a series of optically active bisoxazolines with rigid backbones and different chelate sizes were synthesized. The effect of their chelate sizes on the enantioselectivity was investigated in the asymmetric aziridination. The results indicate that tuning chelate size can not only change the enantioselectivity, but also change the enantiofacial selectivity completely.

AB - Chiral bisoxazolines have been widely applied ligands to asymmetric catalysis and a series of optically active bisoxazolines with rigid backbones and different chelate sizes were synthesized. The effect of their chelate sizes on the enantioselectivity was investigated in the asymmetric aziridination. The results indicate that tuning chelate size can not only change the enantioselectivity, but also change the enantiofacial selectivity completely.

KW - Asymmetric aziridination

KW - Bisoxazoline

KW - Chelate size

KW - Enantioselectivity

KW - Ligand

UR - https://www.scopus.com/pages/publications/33744995559

M3 - Article

AN - SCOPUS:33744995559

SN - 0253-2786

VL - 26

SP - 568

EP - 572

JO - Chinese Journal of Organic Chemistry

JF - Chinese Journal of Organic Chemistry

IS - 4

ER -

Effect of chelate size of bisoxazolines on the enantioselectivity of the asymmetric aziridination

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