Easily Synthesized Ru Catalyst Efficiently Converts Carbonyl Compounds and Ammonia into Primary Amines

Jia Sheng Pan; Rui Zhang; Shuang Shuang Ma; Li Jun Han; Bao Hua Xu

doi:10.1002/slct.202002795

Easily Synthesized Ru Catalyst Efficiently Converts Carbonyl Compounds and Ammonia into Primary Amines

Jia Sheng Pan
, Rui Zhang^*
, Shuang Shuang Ma
, Li Jun Han
, Bao Hua Xu^*

^*此作品的通讯作者

East China University of Science and Technology
Chinese Academy of Sciences
University of Chinese Academy of Sciences

科研成果: 期刊稿件 › 文章 › 同行评审

6 引用（Scopus）

摘要

An easily synthesized ruthenium(II) complex was developed for the direct reductive amination of both aldehydes and ketones with H₂ and ammonia. The intramolecular carboxylate-assisted hydrogenation fashion was found compatible with the amination between carbonyl substrates and ammonia, enabling a high selectivity toward primary amines. Varied primary amines were obtained with a turnover numbers (TON) up to 376.

源语言	英语
页（从-至）	10933-10938
页数	6
期刊	ChemistrySelect
卷	5
期	35
DOI	https://doi.org/10.1002/slct.202002795
出版状态	已出版 - 22 9月 2020
已对外发布	是

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title = "Easily Synthesized Ru Catalyst Efficiently Converts Carbonyl Compounds and Ammonia into Primary Amines",

abstract = "An easily synthesized ruthenium(II) complex was developed for the direct reductive amination of both aldehydes and ketones with H2 and ammonia. The intramolecular carboxylate-assisted hydrogenation fashion was found compatible with the amination between carbonyl substrates and ammonia, enabling a high selectivity toward primary amines. Varied primary amines were obtained with a turnover numbers (TON) up to 376.",

keywords = "Homogeneous catalysis, Primary amines, Reductive amination, Ruthenium",

author = "Pan, \{Jia Sheng\} and Rui Zhang and Ma, \{Shuang Shuang\} and Han, \{Li Jun\} and Xu, \{Bao Hua\}",

note = "Publisher Copyright: {\textcopyright} 2020 Wiley-VCH GmbH",

year = "2020",

month = sep,

day = "22",

doi = "10.1002/slct.202002795",

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T1 - Easily Synthesized Ru Catalyst Efficiently Converts Carbonyl Compounds and Ammonia into Primary Amines

AU - Pan, Jia Sheng

AU - Zhang, Rui

AU - Ma, Shuang Shuang

AU - Han, Li Jun

AU - Xu, Bao Hua

PY - 2020/9/22

Y1 - 2020/9/22

N2 - An easily synthesized ruthenium(II) complex was developed for the direct reductive amination of both aldehydes and ketones with H2 and ammonia. The intramolecular carboxylate-assisted hydrogenation fashion was found compatible with the amination between carbonyl substrates and ammonia, enabling a high selectivity toward primary amines. Varied primary amines were obtained with a turnover numbers (TON) up to 376.

AB - An easily synthesized ruthenium(II) complex was developed for the direct reductive amination of both aldehydes and ketones with H2 and ammonia. The intramolecular carboxylate-assisted hydrogenation fashion was found compatible with the amination between carbonyl substrates and ammonia, enabling a high selectivity toward primary amines. Varied primary amines were obtained with a turnover numbers (TON) up to 376.

KW - Homogeneous catalysis

KW - Primary amines

KW - Reductive amination

KW - Ruthenium

UR - https://www.scopus.com/pages/publications/85091290866

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DO - 10.1002/slct.202002795

M3 - Article

AN - SCOPUS:85091290866

SN - 2365-6549

VL - 5

SP - 10933

EP - 10938

JO - ChemistrySelect

JF - ChemistrySelect

IS - 35

ER -

Easily Synthesized Ru Catalyst Efficiently Converts Carbonyl Compounds and Ammonia into Primary Amines

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