Direct synthesis, crystal structures and thermal analyses of the two-dimensional Cu(ntp)2(H2O)4 crystal (ntp=2-nitroterephthalate)

Jin Yu Guo; Tong Lai Zhang; Jian Guo Zhang; Yan Hong Liu; Kai Bei Yu

Direct synthesis, crystal structures and thermal analyses of the two-dimensional Cu(ntp)₂(H₂O)₄ crystal (ntp=2-nitroterephthalate)

Jin Yu Guo^*
, Tong Lai Zhang
, Jian Guo Zhang
, Yan Hong Liu
, Kai Bei Yu

^*此作品的通讯作者

机电学院

Beijing Institute of Technology
Chinese Academy of Sciences

科研成果: 期刊稿件 › 文章 › 同行评审

3 引用（Scopus）

摘要

The Cu(ntp)₂(H₂O)₄ coordination compound has been synthesized by direct method and its crystal has been cultured and characterized by X-ray single crystal structural analysis. The crystal is formulated as C₁₆H₁₆CuN₂O₁₆ and crystallized in monoclinic system, space group C2/c, with a=2.2665(7) nm, b=0.7068(2) nm, c=1.575 5(4) nm, β=126.42(1)°, V=2.030 8(13) nm ³, D_c=1.818 g·cm³. Based on DSC and TG-DTG analyses, the thermal decomposition mechanism of Cu(ntp) ₂(H₂O)₄ is predicted that it loses its four coordinated water molecules followed by a large weight loss and formation of copper oxide on heating.

源语言	英语
页（从-至）	995-999
页数	5
期刊	Chinese Journal of Inorganic Chemistry
卷	22
期	6
出版状态	已出版 - 6月 2006

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引用此

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title = "Direct synthesis, crystal structures and thermal analyses of the two-dimensional Cu(ntp)2(H2O)4 crystal (ntp=2-nitroterephthalate)",

abstract = "The Cu(ntp)2(H2O)4 coordination compound has been synthesized by direct method and its crystal has been cultured and characterized by X-ray single crystal structural analysis. The crystal is formulated as C16H16CuN2O16 and crystallized in monoclinic system, space group C2/c, with a=2.2665(7) nm, b=0.7068(2) nm, c=1.575 5(4) nm, β=126.42(1)°, V=2.030 8(13) nm 3, Dc=1.818 g·cm3. Based on DSC and TG-DTG analyses, the thermal decomposition mechanism of Cu(ntp) 2(H2O)4 is predicted that it loses its four coordinated water molecules followed by a large weight loss and formation of copper oxide on heating.",

keywords = "Crystal structure, Direct synthesis, Thermal decomposition",

author = "Guo, \{Jin Yu\} and Zhang, \{Tong Lai\} and Zhang, \{Jian Guo\} and Liu, \{Yan Hong\} and Yu, \{Kai Bei\}",

year = "2006",

month = jun,

language = "English",

volume = "22",

pages = "995--999",

journal = "Chinese Journal of Inorganic Chemistry",

issn = "1001-4861",

publisher = "Chinese Chemical Society",

number = "6",

}

TY - JOUR

T1 - Direct synthesis, crystal structures and thermal analyses of the two-dimensional Cu(ntp)2(H2O)4 crystal (ntp=2-nitroterephthalate)

AU - Guo, Jin Yu

AU - Zhang, Tong Lai

AU - Zhang, Jian Guo

AU - Liu, Yan Hong

AU - Yu, Kai Bei

PY - 2006/6

Y1 - 2006/6

N2 - The Cu(ntp)2(H2O)4 coordination compound has been synthesized by direct method and its crystal has been cultured and characterized by X-ray single crystal structural analysis. The crystal is formulated as C16H16CuN2O16 and crystallized in monoclinic system, space group C2/c, with a=2.2665(7) nm, b=0.7068(2) nm, c=1.575 5(4) nm, β=126.42(1)°, V=2.030 8(13) nm 3, Dc=1.818 g·cm3. Based on DSC and TG-DTG analyses, the thermal decomposition mechanism of Cu(ntp) 2(H2O)4 is predicted that it loses its four coordinated water molecules followed by a large weight loss and formation of copper oxide on heating.

AB - The Cu(ntp)2(H2O)4 coordination compound has been synthesized by direct method and its crystal has been cultured and characterized by X-ray single crystal structural analysis. The crystal is formulated as C16H16CuN2O16 and crystallized in monoclinic system, space group C2/c, with a=2.2665(7) nm, b=0.7068(2) nm, c=1.575 5(4) nm, β=126.42(1)°, V=2.030 8(13) nm 3, Dc=1.818 g·cm3. Based on DSC and TG-DTG analyses, the thermal decomposition mechanism of Cu(ntp) 2(H2O)4 is predicted that it loses its four coordinated water molecules followed by a large weight loss and formation of copper oxide on heating.

KW - Crystal structure

KW - Direct synthesis

KW - Thermal decomposition

UR - https://www.scopus.com/pages/publications/33745603022

M3 - Article

AN - SCOPUS:33745603022

SN - 1001-4861

VL - 22

SP - 995

EP - 999

JO - Chinese Journal of Inorganic Chemistry

JF - Chinese Journal of Inorganic Chemistry

IS - 6

ER -

Direct synthesis, crystal structures and thermal analyses of the two-dimensional Cu(ntp)2(H2O)4 crystal (ntp=2-nitroterephthalate)

摘要

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引用此

Direct synthesis, crystal structures and thermal analyses of the two-dimensional Cu(ntp)₂(H₂O)₄ crystal (ntp=2-nitroterephthalate)