Direct C–H magnesiation of thiophenes with an Mg–Mg-bonded compound

Li Yang; Zhenzhou Sun; Lin Wang; Jianqi Geng; Biao Wu; Xiao Juan Yang

doi:10.1039/d6cc00381h

Direct C–H magnesiation of thiophenes with an Mg–Mg-bonded compound

Li Yang
, Zhenzhou Sun
, Lin Wang
, Jianqi Geng
, Biao Wu
, Xiao Juan Yang^*

^*此作品的通讯作者

Beijing Institute of Technology

科研成果: 期刊稿件 › 文章 › 同行评审

摘要

The reaction of the Mg–Mg-bonded compound [K(thf)3]2[LMg–MgL] (1, L = [(2,6-iPr2C6H3)NC(CH3)]22−) with thiophenes afforded magnesium thienyl complexes (2–11) through ortho C–H magnesiation with the release of H2. This provides an efficient approach to metal thienyl reagents, which can be used to construct functionalized thiophenes, e.g., thienyl alcohols from aldehydes or ketones.

源语言	英语
页（从-至）	7172-7175
页数	4
期刊	Chemical Communications
卷	62
期	27
DOI	https://doi.org/10.1039/d6cc00381h
出版状态	已出版 - 7 4月 2026
已对外发布	是

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title = "Direct C–H magnesiation of thiophenes with an Mg–Mg-bonded compound",

abstract = "The reaction of the Mg–Mg-bonded compound [K(thf)3]2[LMg–MgL] (1, L = [(2,6-iPr2C6H3)NC(CH3)]22−) with thiophenes afforded magnesium thienyl complexes (2–11) through ortho C–H magnesiation with the release of H2. This provides an efficient approach to metal thienyl reagents, which can be used to construct functionalized thiophenes, e.g., thienyl alcohols from aldehydes or ketones.",

author = "Li Yang and Zhenzhou Sun and Lin Wang and Jianqi Geng and Biao Wu and Yang, \{Xiao Juan\}",

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T1 - Direct C–H magnesiation of thiophenes with an Mg–Mg-bonded compound

AU - Yang, Li

AU - Sun, Zhenzhou

AU - Wang, Lin

AU - Geng, Jianqi

AU - Wu, Biao

AU - Yang, Xiao Juan

PY - 2026/4/7

Y1 - 2026/4/7

N2 - The reaction of the Mg–Mg-bonded compound [K(thf)3]2[LMg–MgL] (1, L = [(2,6-iPr2C6H3)NC(CH3)]22−) with thiophenes afforded magnesium thienyl complexes (2–11) through ortho C–H magnesiation with the release of H2. This provides an efficient approach to metal thienyl reagents, which can be used to construct functionalized thiophenes, e.g., thienyl alcohols from aldehydes or ketones.

AB - The reaction of the Mg–Mg-bonded compound [K(thf)3]2[LMg–MgL] (1, L = [(2,6-iPr2C6H3)NC(CH3)]22−) with thiophenes afforded magnesium thienyl complexes (2–11) through ortho C–H magnesiation with the release of H2. This provides an efficient approach to metal thienyl reagents, which can be used to construct functionalized thiophenes, e.g., thienyl alcohols from aldehydes or ketones.

UR - https://www.scopus.com/pages/publications/105033821373

U2 - 10.1039/d6cc00381h

DO - 10.1039/d6cc00381h

M3 - Article

C2 - 41873707

AN - SCOPUS:105033821373

SN - 1359-7345

VL - 62

SP - 7172

EP - 7175

JO - Chemical Communications

JF - Chemical Communications

IS - 27

ER -

Direct C–H magnesiation of thiophenes with an Mg–Mg-bonded compound

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