Di -μazido-k4 N:N-bis-[(azido-kN)(2,9-dimethyl-1,10- phenanthroline-k2 N,N′)nickel(II)]

Ling Ling Li; Tian Fu Liu

doi:10.1107/S1600536807035313

Di -μazido-k⁴ N:N-bis-[(azido-kN)(2,9-dimethyl-1,10- phenanthroline-k² N,N′)nickel(II)]

Ling Ling Li
, Tian Fu Liu^*

^*此作品的通讯作者

化学与化工学院

Beijing Institute of Technology

科研成果: 期刊稿件 › 文章 › 同行评审

1 引用（Scopus）

摘要

The title complex, [Ni2(N3)4(C14H12N2)2], is a centrosymmetric dimer in which each Ni^II atom is coordinated by five N atoms (two from a 2,9-dimethyl-1,10-phenanthroline ligand, two from the bridging azide group and one from the terminal azide) in a slightly distorted square-pyramidal geometry. The Ni⋯Ni distance is 3.2532 (9) Å. In the crystal structure, mol-ecules are linked into one-dimensional chains by C - H⋯N hydrogen bonds and π-π stacking inter-actions [π-π interaction distance = 3.6215 (16) Å].

源语言	英语
页（从-至）	m2211
期刊	Acta Crystallographica Section E: Structure Reports Online
卷	63
期	8
DOI	https://doi.org/10.1107/S1600536807035313
出版状态	已出版 - 31 7月 2007

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@article{2460137be9d146a88769264d49301171,

title = "Di -μazido-k4 N:N-bis-[(azido-kN)(2,9-dimethyl-1,10- phenanthroline-k2 N,N′)nickel(II)]",

abstract = "The title complex, [Ni2(N3)4(C14H12N2)2], is a centrosymmetric dimer in which each NiII atom is coordinated by five N atoms (two from a 2,9-dimethyl-1,10-phenanthroline ligand, two from the bridging azide group and one from the terminal azide) in a slightly distorted square-pyramidal geometry. The Ni⋯Ni distance is 3.2532 (9) {\AA}. In the crystal structure, mol-ecules are linked into one-dimensional chains by C - H⋯N hydrogen bonds and π-π stacking inter-actions [π-π interaction distance = 3.6215 (16) {\AA}].",

author = "Li, \{Ling Ling\} and Liu, \{Tian Fu\}",

year = "2007",

month = jul,

day = "31",

doi = "10.1107/S1600536807035313",

language = "English",

volume = "63",

pages = "m2211",

journal = "Acta Crystallographica Section E: Structure Reports Online",

issn = "1600-5368",

publisher = "International Union of Crystallography",

number = "8",

}

TY - JOUR

T1 - Di -μazido-k4 N:N-bis-[(azido-kN)(2,9-dimethyl-1,10- phenanthroline-k2 N,N′)nickel(II)]

AU - Li, Ling Ling

AU - Liu, Tian Fu

PY - 2007/7/31

Y1 - 2007/7/31

N2 - The title complex, [Ni2(N3)4(C14H12N2)2], is a centrosymmetric dimer in which each NiII atom is coordinated by five N atoms (two from a 2,9-dimethyl-1,10-phenanthroline ligand, two from the bridging azide group and one from the terminal azide) in a slightly distorted square-pyramidal geometry. The Ni⋯Ni distance is 3.2532 (9) Å. In the crystal structure, mol-ecules are linked into one-dimensional chains by C - H⋯N hydrogen bonds and π-π stacking inter-actions [π-π interaction distance = 3.6215 (16) Å].

AB - The title complex, [Ni2(N3)4(C14H12N2)2], is a centrosymmetric dimer in which each NiII atom is coordinated by five N atoms (two from a 2,9-dimethyl-1,10-phenanthroline ligand, two from the bridging azide group and one from the terminal azide) in a slightly distorted square-pyramidal geometry. The Ni⋯Ni distance is 3.2532 (9) Å. In the crystal structure, mol-ecules are linked into one-dimensional chains by C - H⋯N hydrogen bonds and π-π stacking inter-actions [π-π interaction distance = 3.6215 (16) Å].

UR - https://www.scopus.com/pages/publications/34547818210

U2 - 10.1107/S1600536807035313

DO - 10.1107/S1600536807035313

M3 - Article

AN - SCOPUS:34547818210

SN - 1600-5368

VL - 63

SP - m2211

JO - Acta Crystallographica Section E: Structure Reports Online

JF - Acta Crystallographica Section E: Structure Reports Online

IS - 8

ER -

Di -μazido-k4 N:N-bis-[(azido-kN)(2,9-dimethyl-1,10- phenanthroline-k2 N,N′)nickel(II)]

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Di -μazido-k⁴ N:N-bis-[(azido-kN)(2,9-dimethyl-1,10- phenanthroline-k² N,N′)nickel(II)]