TY - JOUR
T1 - Crystal structure and chirality of adenosine-5′-diphosphate coordination complex
AU - Zhou, Pei
AU - Wang, Chong
AU - Shi, Rufei
AU - Sheng, Chuanfang
AU - Li, Hui
N1 - Publisher Copyright:
© 2015 Elsevier B.V.
PY - 2016/2
Y1 - 2016/2
N2 - The first neutral coordination complex of adenosine-5′-diphosphate (ADP) with transition metal Cu(II) ion, [Cu(phen)(H2ADP)(NO3)]·H2O (ADP-Cu) (ADP = adenosine-5′-diphosphate, phen = 1, 10-phenanthroline monohydrate) has been synthesized and investigated by X-ray single-crystal diffraction method. Based on its crystal structure and supramolecular assembly analysis, the molecular and supramolecular chirality of ADP-Cu was studied comprehensively by liquid- and solid-state circular dichroism (CD) spectroscopy. It is the first example of the study about the chirality and supramolecular chirality for polyphosphate nucleotide coordination complex.
AB - The first neutral coordination complex of adenosine-5′-diphosphate (ADP) with transition metal Cu(II) ion, [Cu(phen)(H2ADP)(NO3)]·H2O (ADP-Cu) (ADP = adenosine-5′-diphosphate, phen = 1, 10-phenanthroline monohydrate) has been synthesized and investigated by X-ray single-crystal diffraction method. Based on its crystal structure and supramolecular assembly analysis, the molecular and supramolecular chirality of ADP-Cu was studied comprehensively by liquid- and solid-state circular dichroism (CD) spectroscopy. It is the first example of the study about the chirality and supramolecular chirality for polyphosphate nucleotide coordination complex.
KW - Chirality
KW - Polyphosphate nucleotide complex
KW - Single crystal structure
KW - Solid-state circular dichroism spectroscopy
KW - Supramolecular assembly
UR - https://www.scopus.com/pages/publications/84950265230
U2 - 10.1016/j.inoche.2015.12.003
DO - 10.1016/j.inoche.2015.12.003
M3 - Article
AN - SCOPUS:84950265230
SN - 1387-7003
VL - 64
SP - 1
EP - 4
JO - Inorganic Chemistry Communications
JF - Inorganic Chemistry Communications
ER -