Controllable syntheses of two structurally new {AsW9O33}-mediated silver alkynyl clusters

Qingqing Liu; Yeqin Feng; Tianfu Liu; Mengyun Zhao; Yurui Li; Hongjin Lv; Guo Yu Yang

doi:10.1039/d5nr03313f

Controllable syntheses of two structurally new {AsW₉O₃₃}-mediated silver alkynyl clusters

Qingqing Liu
, Yeqin Feng
, Tianfu Liu^*
, Mengyun Zhao
, Yurui Li
, Hongjin Lv^*
, Guo Yu Yang

^*此作品的通讯作者

Beijing Institute of Technology

科研成果: 期刊稿件 › 文章 › 同行评审

1 引用（Scopus）

摘要

In this work, two structurally new silver alkynyl clusters, [(AsW₉O₃₃)₂@Ag₄₈(NO₃)₆(^tBuC = C)₂₄(DMF)₆]·3CH₃CN (1) and [(AsW₉O₃₃)₂@Ag₅₆(NO₃)₄Cl₂(^tBuC C)₃₂]_n (2), were successfully synthesized using the trilacunary B-α-[AsW₉O₃₃]⁹⁻ as an anionic template via a facile one-pot solvothermal approach. The molecular structures of clusters 1 and 2 can be controlled using different mixed reaction solvents. Compounds 1 and 2 also demonstrate efficient photothermal conversion properties and notable catalytic activities towards the detoxification of 4-nitrophenol.

源语言	英语
页（从-至）	21475-21480
页数	6
期刊	Nanoscale
卷	17
期	37
DOI	https://doi.org/10.1039/d5nr03313f
出版状态	已出版 - 25 9月 2025
已对外发布	是

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10.1039/d5nr03313f

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@article{520d084f95814f49a361d10b3c217ee3,

title = "Controllable syntheses of two structurally new \{AsW9O33\}-mediated silver alkynyl clusters",

abstract = "In this work, two structurally new silver alkynyl clusters, [(AsW9O33)2@Ag48(NO3)6(tBuC = C)24(DMF)6]·3CH3CN (1) and [(AsW9O33)2@Ag56(NO3)4Cl2(tBuC C)32]n (2), were successfully synthesized using the trilacunary B-α-[AsW9O33]9− as an anionic template via a facile one-pot solvothermal approach. The molecular structures of clusters 1 and 2 can be controlled using different mixed reaction solvents. Compounds 1 and 2 also demonstrate efficient photothermal conversion properties and notable catalytic activities towards the detoxification of 4-nitrophenol.",

author = "Qingqing Liu and Yeqin Feng and Tianfu Liu and Mengyun Zhao and Yurui Li and Hongjin Lv and Yang, \{Guo Yu\}",

note = "Publisher Copyright: {\textcopyright} 2025 The Royal Society of Chemistry.",

year = "2025",

month = sep,

day = "25",

doi = "10.1039/d5nr03313f",

language = "English",

volume = "17",

pages = "21475--21480",

journal = "Nanoscale",

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publisher = "Royal Society of Chemistry",

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}

TY - JOUR

T1 - Controllable syntheses of two structurally new {AsW9O33}-mediated silver alkynyl clusters

AU - Liu, Qingqing

AU - Feng, Yeqin

AU - Liu, Tianfu

AU - Zhao, Mengyun

AU - Li, Yurui

AU - Lv, Hongjin

AU - Yang, Guo Yu

PY - 2025/9/25

Y1 - 2025/9/25

N2 - In this work, two structurally new silver alkynyl clusters, [(AsW9O33)2@Ag48(NO3)6(tBuC = C)24(DMF)6]·3CH3CN (1) and [(AsW9O33)2@Ag56(NO3)4Cl2(tBuC C)32]n (2), were successfully synthesized using the trilacunary B-α-[AsW9O33]9− as an anionic template via a facile one-pot solvothermal approach. The molecular structures of clusters 1 and 2 can be controlled using different mixed reaction solvents. Compounds 1 and 2 also demonstrate efficient photothermal conversion properties and notable catalytic activities towards the detoxification of 4-nitrophenol.

AB - In this work, two structurally new silver alkynyl clusters, [(AsW9O33)2@Ag48(NO3)6(tBuC = C)24(DMF)6]·3CH3CN (1) and [(AsW9O33)2@Ag56(NO3)4Cl2(tBuC C)32]n (2), were successfully synthesized using the trilacunary B-α-[AsW9O33]9− as an anionic template via a facile one-pot solvothermal approach. The molecular structures of clusters 1 and 2 can be controlled using different mixed reaction solvents. Compounds 1 and 2 also demonstrate efficient photothermal conversion properties and notable catalytic activities towards the detoxification of 4-nitrophenol.

UR - https://www.scopus.com/pages/publications/105017062534

U2 - 10.1039/d5nr03313f

DO - 10.1039/d5nr03313f

M3 - Article

C2 - 40905247

AN - SCOPUS:105017062534

SN - 2040-3364

VL - 17

SP - 21475

EP - 21480

JO - Nanoscale

JF - Nanoscale

IS - 37

ER -

Controllable syntheses of two structurally new {AsW9O33}-mediated silver alkynyl clusters

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Controllable syntheses of two structurally new {AsW₉O₃₃}-mediated silver alkynyl clusters