Controllable syntheses of {SbW9O33}-sandwiched silver clusters induced by external phosphine ligands towards 4-nitrophenol reduction

Wanting Sun; Lan Deng; Mengyun Zhao; Tianfu Liu; Hongjin Lv

doi:10.1016/j.cclet.2025.111416

Controllable syntheses of {SbW₉O₃₃}-sandwiched silver clusters induced by external phosphine ligands towards 4-nitrophenol reduction

Wanting Sun
, Lan Deng^*
, Mengyun Zhao
, Tianfu Liu
, Hongjin Lv

^*此作品的通讯作者

Beijing Institute of Technology

科研成果: 期刊稿件 › 文章 › 同行评审

1 引用（Scopus）

摘要

In this work, we report the controllable synthesis and characterization of four atomically precise silver clusters, Ag₁₈(SbW₉O₃₃)₂(DPPP)₈ (1, DPPP = 1,3-bis(diphenyphosphino)propane), Ag₁₈(SbW₉O₃₃)₂(DPPB)₈ (2, DPPB = 1,4-bis(diphenylphosphino)butane), Ag₁₈(SbW₉O₃₃)₂(DPPPe)₈ (3, DPPPe = 1,5-bis(diphenylphosphino)pentane), and Ag₁₈(SbW₉O₃₃)₂(TPP)₁₄ (4, TPP = triphenylphosphine) by using a facile one-pot solvothermal approach. The resulting four Ag clusters exhibit similar lacunary [SbW₉O₃₃]^9‒ ({SbW₉O₃₃})-sandwiched structures, which can be adjusted by the external different phosphine ligands. In addition, all four clusters display variable physicochemical and catalytic performance, correlating well to their distinct molecular structures.

源语言	英语
期刊论文编号	111416
期刊	Chinese Chemical Letters
卷	37
期	9
DOI	https://doi.org/10.1016/j.cclet.2025.111416
出版状态	已出版 - 9月 2026
已对外发布	是

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10.1016/j.cclet.2025.111416

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@article{09773764adc94b069c75336286580c49,

title = "Controllable syntheses of \{SbW9O33\}-sandwiched silver clusters induced by external phosphine ligands towards 4-nitrophenol reduction",

abstract = "In this work, we report the controllable synthesis and characterization of four atomically precise silver clusters, Ag18(SbW9O33)2(DPPP)8 (1, DPPP = 1,3-bis(diphenyphosphino)propane), Ag18(SbW9O33)2(DPPB)8 (2, DPPB = 1,4-bis(diphenylphosphino)butane), Ag18(SbW9O33)2(DPPPe)8 (3, DPPPe = 1,5-bis(diphenylphosphino)pentane), and Ag18(SbW9O33)2(TPP)14 (4, TPP = triphenylphosphine) by using a facile one-pot solvothermal approach. The resulting four Ag clusters exhibit similar lacunary [SbW9O33]9‒ (\{SbW9O33\})-sandwiched structures, which can be adjusted by the external different phosphine ligands. In addition, all four clusters display variable physicochemical and catalytic performance, correlating well to their distinct molecular structures.",

keywords = "4-Nitrophenol reduction, Photoluminescence, Photothermal conversion, Polyoxometalates, Silver nanoclusters",

author = "Wanting Sun and Lan Deng and Mengyun Zhao and Tianfu Liu and Hongjin Lv",

note = "Publisher Copyright: {\textcopyright} 2026",

year = "2026",

month = sep,

doi = "10.1016/j.cclet.2025.111416",

language = "English",

volume = "37",

journal = "Chinese Chemical Letters",

issn = "1001-8417",

publisher = "Elsevier B.V.",

number = "9",

}

TY - JOUR

T1 - Controllable syntheses of {SbW9O33}-sandwiched silver clusters induced by external phosphine ligands towards 4-nitrophenol reduction

AU - Sun, Wanting

AU - Deng, Lan

AU - Zhao, Mengyun

AU - Liu, Tianfu

AU - Lv, Hongjin

PY - 2026/9

Y1 - 2026/9

N2 - In this work, we report the controllable synthesis and characterization of four atomically precise silver clusters, Ag18(SbW9O33)2(DPPP)8 (1, DPPP = 1,3-bis(diphenyphosphino)propane), Ag18(SbW9O33)2(DPPB)8 (2, DPPB = 1,4-bis(diphenylphosphino)butane), Ag18(SbW9O33)2(DPPPe)8 (3, DPPPe = 1,5-bis(diphenylphosphino)pentane), and Ag18(SbW9O33)2(TPP)14 (4, TPP = triphenylphosphine) by using a facile one-pot solvothermal approach. The resulting four Ag clusters exhibit similar lacunary [SbW9O33]9‒ ({SbW9O33})-sandwiched structures, which can be adjusted by the external different phosphine ligands. In addition, all four clusters display variable physicochemical and catalytic performance, correlating well to their distinct molecular structures.

AB - In this work, we report the controllable synthesis and characterization of four atomically precise silver clusters, Ag18(SbW9O33)2(DPPP)8 (1, DPPP = 1,3-bis(diphenyphosphino)propane), Ag18(SbW9O33)2(DPPB)8 (2, DPPB = 1,4-bis(diphenylphosphino)butane), Ag18(SbW9O33)2(DPPPe)8 (3, DPPPe = 1,5-bis(diphenylphosphino)pentane), and Ag18(SbW9O33)2(TPP)14 (4, TPP = triphenylphosphine) by using a facile one-pot solvothermal approach. The resulting four Ag clusters exhibit similar lacunary [SbW9O33]9‒ ({SbW9O33})-sandwiched structures, which can be adjusted by the external different phosphine ligands. In addition, all four clusters display variable physicochemical and catalytic performance, correlating well to their distinct molecular structures.

KW - 4-Nitrophenol reduction

KW - Photoluminescence

KW - Photothermal conversion

KW - Polyoxometalates

KW - Silver nanoclusters

UR - https://www.scopus.com/pages/publications/105043120294

U2 - 10.1016/j.cclet.2025.111416

DO - 10.1016/j.cclet.2025.111416

M3 - Article

AN - SCOPUS:105043120294

SN - 1001-8417

VL - 37

JO - Chinese Chemical Letters

JF - Chinese Chemical Letters

IS - 9

M1 - 111416

ER -

Controllable syntheses of {SbW9O33}-sandwiched silver clusters induced by external phosphine ligands towards 4-nitrophenol reduction

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Controllable syntheses of {SbW₉O₃₃}-sandwiched silver clusters induced by external phosphine ligands towards 4-nitrophenol reduction