Construction of Polynitro Compounds as High-Performance Oxidizers via a Two-Step Nitration of Various Functional Groups

Gang Zhao; Dheeraj Kumar; Ping Yin; Chunlin He; Gregory H. Imler; Damon A. Parrish; Jean'ne M. Shreeve

doi:10.1021/acs.orglett.8b04114

Construction of Polynitro Compounds as High-Performance Oxidizers via a Two-Step Nitration of Various Functional Groups

Gang Zhao
, Dheeraj Kumar
, Ping Yin
, Chunlin He
, Gregory H. Imler
, Damon A. Parrish
, Jean'ne M. Shreeve^*

^*此作品的通讯作者

University of Idaho
Naval Research Laboratory

科研成果: 期刊稿件 › 文章 › 同行评审

86 引用（Scopus）

摘要

An oxygen-rich energetic compound, 1,3-bis(trinitromethyl)-1,2,4-triazole (13), was obtained by a two-step nitration and found to have an excellent crystal density of 1.90 g/cm ³ confirmed by X-ray single-crystal diffraction. This highly dense material, as a green energetic oxidizer, features an attractive positive oxygen balance, an acceptable sensitivity, and a good enthalpy of formation, making it a competitive replacement for AP.

源语言	英语
页（从-至）	1073-1077
页数	5
期刊	Organic Letters
卷	21
期	4
DOI	https://doi.org/10.1021/acs.orglett.8b04114
出版状态	已出版 - 15 2月 2019
已对外发布	是

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abstract = " An oxygen-rich energetic compound, 1,3-bis(trinitromethyl)-1,2,4-triazole (13), was obtained by a two-step nitration and found to have an excellent crystal density of 1.90 g/cm 3 confirmed by X-ray single-crystal diffraction. This highly dense material, as a green energetic oxidizer, features an attractive positive oxygen balance, an acceptable sensitivity, and a good enthalpy of formation, making it a competitive replacement for AP.",

author = "Gang Zhao and Dheeraj Kumar and Ping Yin and Chunlin He and Imler, \{Gregory H.\} and Parrish, \{Damon A.\} and Shreeve, \{Jean'ne M.\}",

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AU - Zhao, Gang

AU - Kumar, Dheeraj

AU - Yin, Ping

AU - He, Chunlin

AU - Imler, Gregory H.

AU - Parrish, Damon A.

AU - Shreeve, Jean'ne M.

PY - 2019/2/15

Y1 - 2019/2/15

N2 - An oxygen-rich energetic compound, 1,3-bis(trinitromethyl)-1,2,4-triazole (13), was obtained by a two-step nitration and found to have an excellent crystal density of 1.90 g/cm 3 confirmed by X-ray single-crystal diffraction. This highly dense material, as a green energetic oxidizer, features an attractive positive oxygen balance, an acceptable sensitivity, and a good enthalpy of formation, making it a competitive replacement for AP.

AB - An oxygen-rich energetic compound, 1,3-bis(trinitromethyl)-1,2,4-triazole (13), was obtained by a two-step nitration and found to have an excellent crystal density of 1.90 g/cm 3 confirmed by X-ray single-crystal diffraction. This highly dense material, as a green energetic oxidizer, features an attractive positive oxygen balance, an acceptable sensitivity, and a good enthalpy of formation, making it a competitive replacement for AP.

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JO - Organic Letters

JF - Organic Letters

IS - 4

ER -

Construction of Polynitro Compounds as High-Performance Oxidizers via a Two-Step Nitration of Various Functional Groups

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