Comparison between hydrogen‐transfer and fluoro‐transfer reactions on the microcanonical unimolecular rate constants

Wen‐Lin ‐L Feng; Shao‐Wen ‐W Zhang; Yan Wang; Jun‐Nan ‐N Wu; Zong‐He ‐H Li

doi:10.1002/cjoc.19950130503

Comparison between hydrogen‐transfer and fluoro‐transfer reactions on the microcanonical unimolecular rate constants

Wen‐Lin ‐L Feng^*
, Shao‐Wen ‐W Zhang
, Yan Wang
, Jun‐Nan ‐N Wu
, Zong‐He ‐H Li

^*此作品的通讯作者

Beijing Normal University

科研成果: 期刊稿件 › 文章 › 同行评审

摘要

The microcanonical rate constants for the hydrogen‐transfer process of HCCF (reaction 7) and the fluoro‐transfer process of FCCF (reaction 8) are carried out with tunneling correction and curvature correction. The results show that the tunneling effects and curvature effects on the rate constant of reaction 7 is quite different from that of reaction 8. The rate constants for different rotational states are also studied for these reactions.

源语言	英语
页（从-至）	391-395
页数	5
期刊	Chinese Journal of Chemistry
卷	13
期	5
DOI	https://doi.org/10.1002/cjoc.19950130503
出版状态	已出版 - 9月 1995
已对外发布	是

访问文件

10.1002/cjoc.19950130503

其它文件与链接

链接到 Scopus 的出版物

引用此

@article{e51cbe0a45e9468480ccd05ab1beb6e6,

title = "Comparison between hydrogen‐transfer and fluoro‐transfer reactions on the microcanonical unimolecular rate constants",

abstract = "The microcanonical rate constants for the hydrogen‐transfer process of HCCF (reaction 7) and the fluoro‐transfer process of FCCF (reaction 8) are carried out with tunneling correction and curvature correction. The results show that the tunneling effects and curvature effects on the rate constant of reaction 7 is quite different from that of reaction 8. The rate constants for different rotational states are also studied for these reactions.",

keywords = "Microcanonical rate constant, curvature correction, tunneling effect",

author = "Feng, \{Wen‐Lin ‐L\} and Zhang, \{Shao‐Wen ‐W\} and Yan Wang and Wu, \{Jun‐Nan ‐N\} and Li, \{Zong‐He ‐H\}",

year = "1995",

month = sep,

doi = "10.1002/cjoc.19950130503",

language = "English",

volume = "13",

pages = "391--395",

journal = "Chinese Journal of Chemistry",

issn = "1001-604X",

publisher = "John Wiley and Sons Inc.",

number = "5",

}

TY - JOUR

T1 - Comparison between hydrogen‐transfer and fluoro‐transfer reactions on the microcanonical unimolecular rate constants

AU - Feng, Wen‐Lin ‐L

AU - Zhang, Shao‐Wen ‐W

AU - Wang, Yan

AU - Wu, Jun‐Nan ‐N

AU - Li, Zong‐He ‐H

PY - 1995/9

Y1 - 1995/9

N2 - The microcanonical rate constants for the hydrogen‐transfer process of HCCF (reaction 7) and the fluoro‐transfer process of FCCF (reaction 8) are carried out with tunneling correction and curvature correction. The results show that the tunneling effects and curvature effects on the rate constant of reaction 7 is quite different from that of reaction 8. The rate constants for different rotational states are also studied for these reactions.

AB - The microcanonical rate constants for the hydrogen‐transfer process of HCCF (reaction 7) and the fluoro‐transfer process of FCCF (reaction 8) are carried out with tunneling correction and curvature correction. The results show that the tunneling effects and curvature effects on the rate constant of reaction 7 is quite different from that of reaction 8. The rate constants for different rotational states are also studied for these reactions.

KW - Microcanonical rate constant

KW - curvature correction

KW - tunneling effect

UR - https://www.scopus.com/pages/publications/84984369487

U2 - 10.1002/cjoc.19950130503

DO - 10.1002/cjoc.19950130503

M3 - Article

AN - SCOPUS:84984369487

SN - 1001-604X

VL - 13

SP - 391

EP - 395

JO - Chinese Journal of Chemistry

JF - Chinese Journal of Chemistry

IS - 5

ER -

Comparison between hydrogen‐transfer and fluoro‐transfer reactions on the microcanonical unimolecular rate constants

摘要

访问文件

其它文件与链接

指纹

引用此