Cobalt(III)-mediated disulfuration and hydrosulfuration of alkynes

Bao Hua Xu; Xu Qing Peng; Zhi Wei Xu; Yi Zhi Li; Hong Yan

doi:10.1021/ic801199e

Cobalt(III)-mediated disulfuration and hydrosulfuration of alkynes

Bao Hua Xu
, Xu Qing Peng
, Zhi Wei Xu
, Yi Zhi Li
, Hong Yan^*

^*此作品的通讯作者

Nanjing University

科研成果: 期刊稿件 › 文章 › 同行评审

26 引用（Scopus）

摘要

Disulfuration and hydrosulfuration of alkynes mediated by an unusual square-planar tetrathiolate cobalt(III) complex [Cp₂Co] ⁺[Co(S₂C₂B₁₀H₁₀) ₂]^-, 1, lead to a series of cobalt-free carboranyl vinyl sulfides 2-9. All new complexes 1, 2, 3, 4, 5, 6, 7, 8, and 9 were characterized by NMR spectroscopy (¹H, ¹¹B, ¹³C), and X-ray structural analyses were performed for 1, 2, 3, 5, 6, 7, and 9.

源语言	英语
页（从-至）	7928-7933
页数	6
期刊	Inorganic Chemistry
卷	47
期	17
DOI	https://doi.org/10.1021/ic801199e
出版状态	已出版 - 1 9月 2008
已对外发布	是

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title = "Cobalt(III)-mediated disulfuration and hydrosulfuration of alkynes",

abstract = "Disulfuration and hydrosulfuration of alkynes mediated by an unusual square-planar tetrathiolate cobalt(III) complex [Cp2Co] +[Co(S2C2B10H10) 2]-, 1, lead to a series of cobalt-free carboranyl vinyl sulfides 2-9. All new complexes 1, 2, 3, 4, 5, 6, 7, 8, and 9 were characterized by NMR spectroscopy (1H, 11B, 13C), and X-ray structural analyses were performed for 1, 2, 3, 5, 6, 7, and 9.",

author = "Xu, \{Bao Hua\} and Peng, \{Xu Qing\} and Xu, \{Zhi Wei\} and Li, \{Yi Zhi\} and Hong Yan",

year = "2008",

month = sep,

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doi = "10.1021/ic801199e",

language = "English",

volume = "47",

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journal = "Inorganic Chemistry",

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T1 - Cobalt(III)-mediated disulfuration and hydrosulfuration of alkynes

AU - Xu, Bao Hua

AU - Peng, Xu Qing

AU - Xu, Zhi Wei

AU - Li, Yi Zhi

AU - Yan, Hong

PY - 2008/9/1

Y1 - 2008/9/1

N2 - Disulfuration and hydrosulfuration of alkynes mediated by an unusual square-planar tetrathiolate cobalt(III) complex [Cp2Co] +[Co(S2C2B10H10) 2]-, 1, lead to a series of cobalt-free carboranyl vinyl sulfides 2-9. All new complexes 1, 2, 3, 4, 5, 6, 7, 8, and 9 were characterized by NMR spectroscopy (1H, 11B, 13C), and X-ray structural analyses were performed for 1, 2, 3, 5, 6, 7, and 9.

AB - Disulfuration and hydrosulfuration of alkynes mediated by an unusual square-planar tetrathiolate cobalt(III) complex [Cp2Co] +[Co(S2C2B10H10) 2]-, 1, lead to a series of cobalt-free carboranyl vinyl sulfides 2-9. All new complexes 1, 2, 3, 4, 5, 6, 7, 8, and 9 were characterized by NMR spectroscopy (1H, 11B, 13C), and X-ray structural analyses were performed for 1, 2, 3, 5, 6, 7, and 9.

UR - https://www.scopus.com/pages/publications/51849151584

U2 - 10.1021/ic801199e

DO - 10.1021/ic801199e

M3 - Article

AN - SCOPUS:51849151584

SN - 0020-1669

VL - 47

SP - 7928

EP - 7933

JO - Inorganic Chemistry

JF - Inorganic Chemistry

IS - 17

ER -

Cobalt(III)-mediated disulfuration and hydrosulfuration of alkynes

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