Charge-transfer complex crystal based on extended-π-conjugated acceptor and sulfur-bridged annulene: Charge-transfer interaction and remarkable high ambipolar transport characteristics

Yunke Qin; Jing Zhang; Xiaoyan Zheng; Hua Geng; Guangyao Zhao; Wei Xu; Wenping Hu; Zhigang Shuai; Daoben Zhu

doi:10.1002/adma.201400056

Charge-transfer complex crystal based on extended-π-conjugated acceptor and sulfur-bridged annulene: Charge-transfer interaction and remarkable high ambipolar transport characteristics

Yunke Qin
, Jing Zhang
, Xiaoyan Zheng
, Hua Geng
, Guangyao Zhao
, Wei Xu^*
, Wenping Hu
, Zhigang Shuai
, Daoben Zhu

^*此作品的通讯作者

CAS - Institute of Chemistry
University of Chinese Academy of Sciences
Tsinghua University

科研成果: 期刊稿件 › 文章 › 同行评审

156 引用（Scopus）

摘要

A single crystal of a novel mixed-stack donor-acceptor complex formed by a tetracyanoquinodimethane derivative with an extended π-conjugated system and a sulfur-bridged annulene displays the highest ambipolar transport behavior among donor-acceptor complexes reported with electron and hole mobilities reaching up to 0.24 and 0.77 cm² V^-1 s^-1, respectively.

源语言	英语
页（从-至）	4093-4099
页数	7
期刊	Advanced Materials
卷	26
期	24
DOI	https://doi.org/10.1002/adma.201400056
出版状态	已出版 - 25 6月 2014
已对外发布	是

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title = "Charge-transfer complex crystal based on extended-π-conjugated acceptor and sulfur-bridged annulene: Charge-transfer interaction and remarkable high ambipolar transport characteristics",

abstract = "A single crystal of a novel mixed-stack donor-acceptor complex formed by a tetracyanoquinodimethane derivative with an extended π-conjugated system and a sulfur-bridged annulene displays the highest ambipolar transport behavior among donor-acceptor complexes reported with electron and hole mobilities reaching up to 0.24 and 0.77 cm2 V-1 s-1, respectively.",

keywords = "ambipolar transport, charge-transfer complexes, co-crystals, field-effect transistor",

author = "Yunke Qin and Jing Zhang and Xiaoyan Zheng and Hua Geng and Guangyao Zhao and Wei Xu and Wenping Hu and Zhigang Shuai and Daoben Zhu",

year = "2014",

month = jun,

day = "25",

doi = "10.1002/adma.201400056",

language = "English",

volume = "26",

pages = "4093--4099",

journal = "Advanced Materials",

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TY - JOUR

T1 - Charge-transfer complex crystal based on extended-π-conjugated acceptor and sulfur-bridged annulene

T2 - Charge-transfer interaction and remarkable high ambipolar transport characteristics

AU - Qin, Yunke

AU - Zhang, Jing

AU - Zheng, Xiaoyan

AU - Geng, Hua

AU - Zhao, Guangyao

AU - Xu, Wei

AU - Hu, Wenping

AU - Shuai, Zhigang

AU - Zhu, Daoben

PY - 2014/6/25

Y1 - 2014/6/25

N2 - A single crystal of a novel mixed-stack donor-acceptor complex formed by a tetracyanoquinodimethane derivative with an extended π-conjugated system and a sulfur-bridged annulene displays the highest ambipolar transport behavior among donor-acceptor complexes reported with electron and hole mobilities reaching up to 0.24 and 0.77 cm2 V-1 s-1, respectively.

AB - A single crystal of a novel mixed-stack donor-acceptor complex formed by a tetracyanoquinodimethane derivative with an extended π-conjugated system and a sulfur-bridged annulene displays the highest ambipolar transport behavior among donor-acceptor complexes reported with electron and hole mobilities reaching up to 0.24 and 0.77 cm2 V-1 s-1, respectively.

KW - ambipolar transport

KW - charge-transfer complexes

KW - co-crystals

KW - field-effect transistor

UR - https://www.scopus.com/pages/publications/84903159096

U2 - 10.1002/adma.201400056

DO - 10.1002/adma.201400056

M3 - Article

AN - SCOPUS:84903159096

SN - 0935-9648

VL - 26

SP - 4093

EP - 4099

JO - Advanced Materials

JF - Advanced Materials

IS - 24

ER -

Charge-transfer complex crystal based on extended-π-conjugated acceptor and sulfur-bridged annulene: Charge-transfer interaction and remarkable high ambipolar transport characteristics

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