TY - JOUR
T1 - Cationic rare earth metal alkyls as novel catalysts for olefin polymerization and copolymerization
AU - Hou, Zhaomin
AU - Luo, Yunjie
AU - Li, Xiaofang
PY - 2006/7/1
Y1 - 2006/7/1
N2 - Cationic rare earth metal alkyl species, generated by the treatment of mono(cyclopentadienyl) bis(alkyl) rare earth metal complexes with 1 equiv. of a borate compound such as [Ph3C][B(C6F5)4], act as an excellent catalyst for the polymerization and copolymerization of various olefins such as ethylene, 1-hexene, styrene, norbornene, dicyclopentadiene, and isoprene. These catalysts show unprecedented activity and regio- and stereo-selectivity and afford a series of new polymers which are difficult to be prepared previously.
AB - Cationic rare earth metal alkyl species, generated by the treatment of mono(cyclopentadienyl) bis(alkyl) rare earth metal complexes with 1 equiv. of a borate compound such as [Ph3C][B(C6F5)4], act as an excellent catalyst for the polymerization and copolymerization of various olefins such as ethylene, 1-hexene, styrene, norbornene, dicyclopentadiene, and isoprene. These catalysts show unprecedented activity and regio- and stereo-selectivity and afford a series of new polymers which are difficult to be prepared previously.
KW - Cationic rare earth metal alkyls
KW - Cyclic olefins
KW - Isoprene
KW - Metallocene catalysis
KW - Olefin polymerization
KW - Styrene
UR - https://www.scopus.com/pages/publications/33745178786
U2 - 10.1016/j.jorganchem.2006.01.055
DO - 10.1016/j.jorganchem.2006.01.055
M3 - Review article
AN - SCOPUS:33745178786
SN - 0022-328X
VL - 691
SP - 3114
EP - 3121
JO - Journal of Organometallic Chemistry
JF - Journal of Organometallic Chemistry
IS - 14
ER -