Catalytic asymmetric hydrogenation of δ-ketoesters: Highly efficient approach to chiral 1,5-diols

Xiao Hui Yang; Jian Hua Xie; Wei Peng Liu; Qi Lin Zhou

doi:10.1002/anie.201303011

Catalytic asymmetric hydrogenation of δ-ketoesters: Highly efficient approach to chiral 1,5-diols

Xiao Hui Yang
, Jian Hua Xie^*
, Wei Peng Liu
, Qi Lin Zhou

^*此作品的通讯作者

Nankai University

科研成果: 期刊稿件 › 文章 › 同行评审

75 引用（Scopus）

摘要

High turnover: An highly efficient catalytic asymmetric hydrogenation of δ-aryl-δ-ketoesters has been realized by using the chiral spiroiridium catalyst (R)-1. Chiral 1,5-diol products are obtained with excellent enantioselectivity and turnover numbers (TONs) as high as 100 000. TOF=turnover frequency.

源语言	英语
页（从-至）	7833-7836
页数	4
期刊	Angewandte Chemie - International Edition
卷	52
期	30
DOI	https://doi.org/10.1002/anie.201303011
出版状态	已出版 - 22 7月 2013
已对外发布	是

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title = "Catalytic asymmetric hydrogenation of δ-ketoesters: Highly efficient approach to chiral 1,5-diols",

abstract = "High turnover: An highly efficient catalytic asymmetric hydrogenation of δ-aryl-δ-ketoesters has been realized by using the chiral spiroiridium catalyst (R)-1. Chiral 1,5-diol products are obtained with excellent enantioselectivity and turnover numbers (TONs) as high as 100 000. TOF=turnover frequency.",

keywords = "asymmetric catalysis, catalyst design, hydrogenation, iridium, synthetic methods",

author = "Yang, \{Xiao Hui\} and Xie, \{Jian Hua\} and Liu, \{Wei Peng\} and Zhou, \{Qi Lin\}",

year = "2013",

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T1 - Catalytic asymmetric hydrogenation of δ-ketoesters

T2 - Highly efficient approach to chiral 1,5-diols

AU - Yang, Xiao Hui

AU - Xie, Jian Hua

AU - Liu, Wei Peng

AU - Zhou, Qi Lin

PY - 2013/7/22

Y1 - 2013/7/22

N2 - High turnover: An highly efficient catalytic asymmetric hydrogenation of δ-aryl-δ-ketoesters has been realized by using the chiral spiroiridium catalyst (R)-1. Chiral 1,5-diol products are obtained with excellent enantioselectivity and turnover numbers (TONs) as high as 100 000. TOF=turnover frequency.

AB - High turnover: An highly efficient catalytic asymmetric hydrogenation of δ-aryl-δ-ketoesters has been realized by using the chiral spiroiridium catalyst (R)-1. Chiral 1,5-diol products are obtained with excellent enantioselectivity and turnover numbers (TONs) as high as 100 000. TOF=turnover frequency.

KW - asymmetric catalysis

KW - catalyst design

KW - hydrogenation

KW - iridium

KW - synthetic methods

UR - https://www.scopus.com/pages/publications/84880394593

U2 - 10.1002/anie.201303011

DO - 10.1002/anie.201303011

M3 - Article

AN - SCOPUS:84880394593

SN - 1433-7851

VL - 52

SP - 7833

EP - 7836

JO - Angewandte Chemie - International Edition

JF - Angewandte Chemie - International Edition

IS - 30

ER -

Catalytic asymmetric hydrogenation of δ-ketoesters: Highly efficient approach to chiral 1,5-diols

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