B3O4(OH) · 0.5(C4H10N2): First organic-inorganic hybrid borate with a neutral layered framework

Guang Zhen Liu; Shou Tian Zheng; Guo Yu Yang

doi:10.1016/j.inoche.2006.09.021

B₃O₄(OH) · 0.5(C₄H₁₀N₂): First organic-inorganic hybrid borate with a neutral layered framework

Guang Zhen Liu
, Shou Tian Zheng
, Guo Yu Yang^*

^*此作品的通讯作者

CAS - Fujian Institute of Research on the Structure of Matter

科研成果: 期刊稿件 › 文章 › 同行评审

44 引用（Scopus）

摘要

A novel hybrid borate B₃O₄(OH) · 0.5(C₄H₁₀N₂) 1 was synthesized under milder hydrothermal conditions. The product was characterized by a combination of elemental analysis, FT-IR, thermogravimetric analysis and powder X-ray diffraction, as well as single-crystal X-ray diffraction studies. The structure consists of two types of inorganic borate helices cohered by piperazine rings, giving rise to a neutral hybrid sheet. The adjacent layers are stacked in a parallel fashion and further stabilized by hydrogen bonding interactions.

源语言	英语
页（从-至）	84-87
页数	4
期刊	Inorganic Chemistry Communications
卷	10
期	1
DOI	https://doi.org/10.1016/j.inoche.2006.09.021
出版状态	已出版 - 1月 2007
已对外发布	是

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@article{70713a497bd249d1b2dbfde577958691,

title = "B3O4(OH) · 0.5(C4H10N2): First organic-inorganic hybrid borate with a neutral layered framework",

abstract = "A novel hybrid borate B3O4(OH) · 0.5(C4H10N2) 1 was synthesized under milder hydrothermal conditions. The product was characterized by a combination of elemental analysis, FT-IR, thermogravimetric analysis and powder X-ray diffraction, as well as single-crystal X-ray diffraction studies. The structure consists of two types of inorganic borate helices cohered by piperazine rings, giving rise to a neutral hybrid sheet. The adjacent layers are stacked in a parallel fashion and further stabilized by hydrogen bonding interactions.",

keywords = "Borates, Crystal structure, Hydrothermal synthesis, Inorganic-organic hybrid",

author = "Liu, \{Guang Zhen\} and Zheng, \{Shou Tian\} and Yang, \{Guo Yu\}",

year = "2007",

month = jan,

doi = "10.1016/j.inoche.2006.09.021",

language = "English",

volume = "10",

pages = "84--87",

journal = "Inorganic Chemistry Communications",

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T1 - B3O4(OH) · 0.5(C4H10N2)

T2 - First organic-inorganic hybrid borate with a neutral layered framework

AU - Liu, Guang Zhen

AU - Zheng, Shou Tian

AU - Yang, Guo Yu

PY - 2007/1

Y1 - 2007/1

N2 - A novel hybrid borate B3O4(OH) · 0.5(C4H10N2) 1 was synthesized under milder hydrothermal conditions. The product was characterized by a combination of elemental analysis, FT-IR, thermogravimetric analysis and powder X-ray diffraction, as well as single-crystal X-ray diffraction studies. The structure consists of two types of inorganic borate helices cohered by piperazine rings, giving rise to a neutral hybrid sheet. The adjacent layers are stacked in a parallel fashion and further stabilized by hydrogen bonding interactions.

AB - A novel hybrid borate B3O4(OH) · 0.5(C4H10N2) 1 was synthesized under milder hydrothermal conditions. The product was characterized by a combination of elemental analysis, FT-IR, thermogravimetric analysis and powder X-ray diffraction, as well as single-crystal X-ray diffraction studies. The structure consists of two types of inorganic borate helices cohered by piperazine rings, giving rise to a neutral hybrid sheet. The adjacent layers are stacked in a parallel fashion and further stabilized by hydrogen bonding interactions.

KW - Borates

KW - Crystal structure

KW - Hydrothermal synthesis

KW - Inorganic-organic hybrid

UR - https://www.scopus.com/pages/publications/33845185993

U2 - 10.1016/j.inoche.2006.09.021

DO - 10.1016/j.inoche.2006.09.021

M3 - Article

AN - SCOPUS:33845185993

SN - 1387-7003

VL - 10

SP - 84

EP - 87

JO - Inorganic Chemistry Communications

JF - Inorganic Chemistry Communications

IS - 1

ER -

B3O4(OH) · 0.5(C4H10N2): First organic-inorganic hybrid borate with a neutral layered framework

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B₃O₄(OH) · 0.5(C₄H₁₀N₂): First organic-inorganic hybrid borate with a neutral layered framework