B12H122–-Based Metal (Cu2+, Ni2+, Zn2+) Complexes as Hypergolic Fuels with Superior Hypergolicity

Zejun Zhang; Yanqiang Zhang; Zhimin Li; Nianming Jiao; Long Liu; Suojiang Zhang

doi:10.1002/ejic.201701206

B₁₂H₁₂^2–-Based Metal (Cu²⁺, Ni²⁺, Zn²⁺) Complexes as Hypergolic Fuels with Superior Hypergolicity

Zejun Zhang
, Yanqiang Zhang^*
, Zhimin Li
, Nianming Jiao
, Long Liu
, Suojiang Zhang

^*此作品的通讯作者

CAS - Institute of Process Engineering
University of Chinese Academy of Sciences
Zhengzhou Institute of Emerging Industrial Technology
Laboratory of Particle Science and Engineering

科研成果: 期刊稿件 › 文章 › 同行评审

46 引用（Scopus）

摘要

In hypergolic propellants, hypergolicity is an extremely important parameter in evaluating fuels. In this study, a new family of hypergolic metal (Cu²⁺, Ni²⁺, Zn²⁺) complexes with B₁₂H₁₂^2– were synthesized and fully characterized. Two of these six complexes exhibited ultrashort ignition delay times (ca. 1 ms), with white fuming nitric acid as the oxidizer, besides good physicochemical properties (decomposition temperatures: 221.8–286.3 °C; densities: 1.215–1.264 g cm^–3). The results demonstrate their promising applications in bipropellant formulations.

源语言	英语
页（从-至）	981-986
页数	6
期刊	European Journal of Inorganic Chemistry
卷	2018
期	8
DOI	https://doi.org/10.1002/ejic.201701206
出版状态	已出版 - 28 2月 2018
已对外发布	是

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title = "B12H122–-Based Metal (Cu2+, Ni2+, Zn2+) Complexes as Hypergolic Fuels with Superior Hypergolicity",

abstract = "In hypergolic propellants, hypergolicity is an extremely important parameter in evaluating fuels. In this study, a new family of hypergolic metal (Cu2+, Ni2+, Zn2+) complexes with B12H122– were synthesized and fully characterized. Two of these six complexes exhibited ultrashort ignition delay times (ca. 1 ms), with white fuming nitric acid as the oxidizer, besides good physicochemical properties (decomposition temperatures: 221.8–286.3 °C; densities: 1.215–1.264 g cm–3). The results demonstrate their promising applications in bipropellant formulations.",

keywords = "Boron, Hypergolic fuels, Ionic liquids, Propellants, Transition metals",

author = "Zejun Zhang and Yanqiang Zhang and Zhimin Li and Nianming Jiao and Long Liu and Suojiang Zhang",

note = "Publisher Copyright: {\textcopyright} 2018 WILEY-VCH Verlag GmbH \& Co. KGaA, Weinheim",

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T1 - B12H122–-Based Metal (Cu2+, Ni2+, Zn2+) Complexes as Hypergolic Fuels with Superior Hypergolicity

AU - Zhang, Zejun

AU - Zhang, Yanqiang

AU - Li, Zhimin

AU - Jiao, Nianming

AU - Liu, Long

AU - Zhang, Suojiang

PY - 2018/2/28

Y1 - 2018/2/28

N2 - In hypergolic propellants, hypergolicity is an extremely important parameter in evaluating fuels. In this study, a new family of hypergolic metal (Cu2+, Ni2+, Zn2+) complexes with B12H122– were synthesized and fully characterized. Two of these six complexes exhibited ultrashort ignition delay times (ca. 1 ms), with white fuming nitric acid as the oxidizer, besides good physicochemical properties (decomposition temperatures: 221.8–286.3 °C; densities: 1.215–1.264 g cm–3). The results demonstrate their promising applications in bipropellant formulations.

AB - In hypergolic propellants, hypergolicity is an extremely important parameter in evaluating fuels. In this study, a new family of hypergolic metal (Cu2+, Ni2+, Zn2+) complexes with B12H122– were synthesized and fully characterized. Two of these six complexes exhibited ultrashort ignition delay times (ca. 1 ms), with white fuming nitric acid as the oxidizer, besides good physicochemical properties (decomposition temperatures: 221.8–286.3 °C; densities: 1.215–1.264 g cm–3). The results demonstrate their promising applications in bipropellant formulations.

KW - Boron

KW - Hypergolic fuels

KW - Ionic liquids

KW - Propellants

KW - Transition metals

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AN - SCOPUS:85041795888

SN - 1434-1948

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SP - 981

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JO - European Journal of Inorganic Chemistry

JF - European Journal of Inorganic Chemistry

IS - 8

ER -

B12H122–-Based Metal (Cu2+, Ni2+, Zn2+) Complexes as Hypergolic Fuels with Superior Hypergolicity

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B₁₂H₁₂^2–-Based Metal (Cu²⁺, Ni²⁺, Zn²⁺) Complexes as Hypergolic Fuels with Superior Hypergolicity