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Bipyridine conformations control the solid-state supramolecular chemistry of zinc(II) phthalocyanine with bipyridines

  • Qingdao Zeng*
  • , Dongxia Wu
  • , Chen Wang
  • , Jun Lu
  • , Baocheng Ma
  • , Chunying Shu
  • , Hongwei Ma
  • , Yan Li
  • , Chunli Bai
  • *此作品的通讯作者
  • CAS - Institute of Chemistry
  • National Center for Nanoscience and Technology

科研成果: 期刊稿件 › 文章 › 同行评审

摘要

Two H-shaped supramolecular complexes (C32H16N 8Zn)2·(C12H12N 2)·0.96H2O (1), (C32H 16N8Zn)2·(C12H 10N2)·(DMF)2 (2), and one T-shaped supramolecular complex C32H16N 8Zn·C13H14N2 (3) have been prepared from zinc(II) phthalocyanine with 1,2-bis(4-pyridyl)ethane (bipy-eta), 1,2-di(4-pyridyl)ethylene (dipy-ete) or 1,3-di(4-pyridyl)propane (dipy-pra), respectively, and characterized by single-crystal X-ray diffraction, electronic absorption spectra and fluorescence spectra; the conformation of the bipyridines plays an important role in the assembly processes.

源语言英语
期刊论文编号38
页(从-至)243-248
页数6
期刊CrystEngComm
卷7
DOI
出版状态已出版 - 24 3月 2005
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