An unprecedented example of a heterotrimetallic main-group [L 2Al2Ge4Li2S7] cluster containing a GeII-GeII donor-acceptor bond

Zhi Yang; Xiaoli Ma; Rainer B. Oswald; Herbert W. Roesky; Chunming Cui; Hans Georg Schmidt; Mathias Noltemeyer

doi:10.1002/anie.200503940

An unprecedented example of a heterotrimetallic main-group [L ₂Al₂Ge₄Li₂S₇] cluster containing a Ge^II-Ge^II donor-acceptor bond

Zhi Yang^*
, Xiaoli Ma
, Rainer B. Oswald
, Herbert W. Roesky
, Chunming Cui
, Hans Georg Schmidt
, Mathias Noltemeyer

^*此作品的通讯作者

University of Göttingen
Nankai University

科研成果: 期刊稿件 › 文章 › 同行评审

20 引用（Scopus）

摘要

(Chemical Equation Presented) Donations accepted : The reaction of [{LAl[(SLi)₂(thf)₂]}₂] (L = HC(CMeNAr) ₂, Ar = 2,6-iPr₂C₆H₃) with GeCl ₂·dioxane yields the novel Ge^II→Ge ^II-containing hetero-trimetallic [L₂Al₂Ge ₄Li₂S₇] cluster, which has a crablike structure (Al gray, Ge magenta, Li orange, S yellow, O green, N blue, C light gray). This cluster is the first aluminum-containing hetero-trimetallic sulfide.

源语言	英语
页（从-至）	2277-2280
页数	4
期刊	Angewandte Chemie - International Edition
卷	45
期	14
DOI	https://doi.org/10.1002/anie.200503940
出版状态	已出版 - 27 3月 2006
已对外发布	是

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title = "An unprecedented example of a heterotrimetallic main-group [L 2Al2Ge4Li2S7] cluster containing a GeII-GeII donor-acceptor bond",

abstract = "(Chemical Equation Presented) Donations accepted : The reaction of [\{LAl[(SLi)2(thf)2]\}2] (L = HC(CMeNAr) 2, Ar = 2,6-iPr2C6H3) with GeCl 2·dioxane yields the novel GeII→Ge II-containing hetero-trimetallic [L2Al2Ge 4Li2S7] cluster, which has a crablike structure (Al gray, Ge magenta, Li orange, S yellow, O green, N blue, C light gray). This cluster is the first aluminum-containing hetero-trimetallic sulfide.",

keywords = "Aluminum, Cluster compounds, Germanium, N ligands, Sulfur",

author = "Zhi Yang and Xiaoli Ma and Oswald, \{Rainer B.\} and Roesky, \{Herbert W.\} and Chunming Cui and Schmidt, \{Hans Georg\} and Mathias Noltemeyer",

year = "2006",

month = mar,

day = "27",

doi = "10.1002/anie.200503940",

language = "English",

volume = "45",

pages = "2277--2280",

journal = "Angewandte Chemie - International Edition",

issn = "1433-7851",

publisher = "John Wiley and Sons Ltd",

number = "14",

}

TY - JOUR

T1 - An unprecedented example of a heterotrimetallic main-group [L 2Al2Ge4Li2S7] cluster containing a GeII-GeII donor-acceptor bond

AU - Yang, Zhi

AU - Ma, Xiaoli

AU - Oswald, Rainer B.

AU - Roesky, Herbert W.

AU - Cui, Chunming

AU - Schmidt, Hans Georg

AU - Noltemeyer, Mathias

PY - 2006/3/27

Y1 - 2006/3/27

N2 - (Chemical Equation Presented) Donations accepted : The reaction of [{LAl[(SLi)2(thf)2]}2] (L = HC(CMeNAr) 2, Ar = 2,6-iPr2C6H3) with GeCl 2·dioxane yields the novel GeII→Ge II-containing hetero-trimetallic [L2Al2Ge 4Li2S7] cluster, which has a crablike structure (Al gray, Ge magenta, Li orange, S yellow, O green, N blue, C light gray). This cluster is the first aluminum-containing hetero-trimetallic sulfide.

AB - (Chemical Equation Presented) Donations accepted : The reaction of [{LAl[(SLi)2(thf)2]}2] (L = HC(CMeNAr) 2, Ar = 2,6-iPr2C6H3) with GeCl 2·dioxane yields the novel GeII→Ge II-containing hetero-trimetallic [L2Al2Ge 4Li2S7] cluster, which has a crablike structure (Al gray, Ge magenta, Li orange, S yellow, O green, N blue, C light gray). This cluster is the first aluminum-containing hetero-trimetallic sulfide.

KW - Aluminum

KW - Cluster compounds

KW - Germanium

KW - N ligands

KW - Sulfur

UR - https://www.scopus.com/pages/publications/33746289863

U2 - 10.1002/anie.200503940

DO - 10.1002/anie.200503940

M3 - Article

AN - SCOPUS:33746289863

SN - 1433-7851

VL - 45

SP - 2277

EP - 2280

JO - Angewandte Chemie - International Edition

JF - Angewandte Chemie - International Edition

IS - 14

ER -

An unprecedented example of a heterotrimetallic main-group [L 2Al2Ge4Li2S7] cluster containing a GeII-GeII donor-acceptor bond

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An unprecedented example of a heterotrimetallic main-group [L ₂Al₂Ge₄Li₂S₇] cluster containing a Ge^II-Ge^II donor-acceptor bond