An n-channel two-dimensional covalent organic framework

Xuesong Ding; Long Chen; Yoshihito Honsho; Xiao Feng; Oraphan Saengsawang; Jingdong Guo; Akinori Saeki; Shu Seki; Stephan Irle; Shigeru Nagase; Vudhichai Parasuk; Donglin Jiang

doi:10.1021/ja2052396

^*此作品的通讯作者

National Institutes of Natural Sciences - Institute for Molecular Science
The University of Osaka
Nagoya University
Chulalongkorn University
Japan Science and Technology Agency

科研成果: 期刊稿件 › 文章 › 同行评审

368 引用（Scopus）

摘要

Co-condensation of metallophthalocyanine with an electron-deficient benzothiadiazole (BTDA) block leads to the formation of a two-dimensional covalent organic framework (2D-NiPc-BTDA COF) that assumes a belt shape and consists of AA stacking of 2D polymer sheets. Integration of BTDA blocks at the edges of a tetragonal metallophthalocyanine COF causes drastic changes in the carrier-transport mode and a switch from a hole-transporting skeleton to an electron-transporting framework. 2D-NiPc-BTDA COF exhibits broad and enhanced absorbance up to 1000 nm, shows panchromatic photoconductivity, is highly sensitive to near-infrared photons, and has excellent electron mobility as high as 0.6 cm² V^-1 s^-1.

源语言	英语
页（从-至）	14510-14513
页数	4
期刊	Journal of the American Chemical Society
卷	133
期	37
DOI	https://doi.org/10.1021/ja2052396
出版状态	已出版 - 21 9月 2011
已对外发布	是

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title = "An n-channel two-dimensional covalent organic framework",

abstract = "Co-condensation of metallophthalocyanine with an electron-deficient benzothiadiazole (BTDA) block leads to the formation of a two-dimensional covalent organic framework (2D-NiPc-BTDA COF) that assumes a belt shape and consists of AA stacking of 2D polymer sheets. Integration of BTDA blocks at the edges of a tetragonal metallophthalocyanine COF causes drastic changes in the carrier-transport mode and a switch from a hole-transporting skeleton to an electron-transporting framework. 2D-NiPc-BTDA COF exhibits broad and enhanced absorbance up to 1000 nm, shows panchromatic photoconductivity, is highly sensitive to near-infrared photons, and has excellent electron mobility as high as 0.6 cm2 V-1 s-1.",

author = "Xuesong Ding and Long Chen and Yoshihito Honsho and Xiao Feng and Oraphan Saengsawang and Jingdong Guo and Akinori Saeki and Shu Seki and Stephan Irle and Shigeru Nagase and Vudhichai Parasuk and Donglin Jiang",

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T1 - An n-channel two-dimensional covalent organic framework

AU - Ding, Xuesong

AU - Chen, Long

AU - Honsho, Yoshihito

AU - Feng, Xiao

AU - Saengsawang, Oraphan

AU - Guo, Jingdong

AU - Saeki, Akinori

AU - Seki, Shu

AU - Irle, Stephan

AU - Nagase, Shigeru

AU - Parasuk, Vudhichai

AU - Jiang, Donglin

PY - 2011/9/21

Y1 - 2011/9/21

N2 - Co-condensation of metallophthalocyanine with an electron-deficient benzothiadiazole (BTDA) block leads to the formation of a two-dimensional covalent organic framework (2D-NiPc-BTDA COF) that assumes a belt shape and consists of AA stacking of 2D polymer sheets. Integration of BTDA blocks at the edges of a tetragonal metallophthalocyanine COF causes drastic changes in the carrier-transport mode and a switch from a hole-transporting skeleton to an electron-transporting framework. 2D-NiPc-BTDA COF exhibits broad and enhanced absorbance up to 1000 nm, shows panchromatic photoconductivity, is highly sensitive to near-infrared photons, and has excellent electron mobility as high as 0.6 cm2 V-1 s-1.

AB - Co-condensation of metallophthalocyanine with an electron-deficient benzothiadiazole (BTDA) block leads to the formation of a two-dimensional covalent organic framework (2D-NiPc-BTDA COF) that assumes a belt shape and consists of AA stacking of 2D polymer sheets. Integration of BTDA blocks at the edges of a tetragonal metallophthalocyanine COF causes drastic changes in the carrier-transport mode and a switch from a hole-transporting skeleton to an electron-transporting framework. 2D-NiPc-BTDA COF exhibits broad and enhanced absorbance up to 1000 nm, shows panchromatic photoconductivity, is highly sensitive to near-infrared photons, and has excellent electron mobility as high as 0.6 cm2 V-1 s-1.

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SP - 14510

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JO - Journal of the American Chemical Society

JF - Journal of the American Chemical Society

IS - 37

ER -

An n-channel two-dimensional covalent organic framework

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