TY - JOUR
T1 - An aluminoborate directed by [Zn(H2O)4]2 + complex
T2 - Synthesis, structure and properties
AU - Pan, Rui
AU - Yang, Bai Bai
AU - Wang, Guo Ming
AU - Yang, Guo Yu
N1 - Publisher Copyright:
© 2016 Elsevier B.V.
PY - 2017/2/1
Y1 - 2017/2/1
N2 - A novel 3D aluminoborate with [Zn(H2O)4]2+ cationic complexes as structure-directing agents (SDAs), namely, [Zn(H2O)4][Al(B5O10)]·0.5(H2O) (1), has been solvothermally prepared and characterized by IR spectroscopy, UV–vis reflection spectroscopy, thermogravimetric (TG) analyses, powder and single crystal X-ray diffraction, respectively. The alternative linkage of AlO4 tetrahedra and B5O10 units produces an open-framework aluminoborate with helical 6- and 8-membered ring (MR) channels, as well as large odd 11-MR channels. The [Zn(H2O)4]2+ templates, generated in situ from solvothermal conditions, are orderly located in the center of the 11-MR channels. The second-harmonic generation (SHG) measurement indicates that 1 exhibits about 0.5 times that of KDP standard (K2HPO4).
AB - A novel 3D aluminoborate with [Zn(H2O)4]2+ cationic complexes as structure-directing agents (SDAs), namely, [Zn(H2O)4][Al(B5O10)]·0.5(H2O) (1), has been solvothermally prepared and characterized by IR spectroscopy, UV–vis reflection spectroscopy, thermogravimetric (TG) analyses, powder and single crystal X-ray diffraction, respectively. The alternative linkage of AlO4 tetrahedra and B5O10 units produces an open-framework aluminoborate with helical 6- and 8-membered ring (MR) channels, as well as large odd 11-MR channels. The [Zn(H2O)4]2+ templates, generated in situ from solvothermal conditions, are orderly located in the center of the 11-MR channels. The second-harmonic generation (SHG) measurement indicates that 1 exhibits about 0.5 times that of KDP standard (K2HPO4).
KW - Aluminoborate
KW - Crystal structure
KW - Nonlinear optical
KW - Solvothermal synthesis
UR - https://www.scopus.com/pages/publications/85008413056
U2 - 10.1016/j.inoche.2016.12.009
DO - 10.1016/j.inoche.2016.12.009
M3 - Article
AN - SCOPUS:85008413056
SN - 1387-7003
VL - 76
SP - 26
EP - 29
JO - Inorganic Chemistry Communications
JF - Inorganic Chemistry Communications
ER -