A Zr-added Dawson-type poly(polyoxometalate)

Hai Lou Li; Chen Lian; Guo Yu Yang

doi:10.1039/d2dt03820j

A Zr-added Dawson-type poly(polyoxometalate)

Hai Lou Li
, Chen Lian
, Guo Yu Yang^*

^*此作品的通讯作者

化学与化工学院

Beijing Institute of Technology

科研成果: 期刊稿件 › 文章 › 同行评审

26 引用（Scopus）

摘要

A novel Zr-added trimer, [H₂N(CH₃)₂]₁₀H₁₄[(Zr₂P₂W₁₆O₆₁)₃]·7H₂O (1), has been made under hydrothermal conditions, and contains the highest number of Zr centers in known Dawson-type poly(POM)s. A remarkable feature of this study is the first discovery of a new type of divacant [α-5,10-P₂W₁₆O₆₀]¹⁴⁻ fragment, which assembles with Zr⁴⁺ ions to form a cyclic trimer. Furthermore, 1 as a heterogeneous catalyst exhibits high activity for the selective oxidative degradation of a sulfur mustard simulant CEES.

源语言	英语
页（从-至）	857-861
页数	5
期刊	Dalton Transactions
卷	52
期	4
DOI	https://doi.org/10.1039/d2dt03820j
出版状态	已出版 - 22 12月 2022

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title = "A Zr-added Dawson-type poly(polyoxometalate)",

abstract = "A novel Zr-added trimer, [H2N(CH3)2]10H14[(Zr2P2W16O61)3]·7H2O (1), has been made under hydrothermal conditions, and contains the highest number of Zr centers in known Dawson-type poly(POM)s. A remarkable feature of this study is the first discovery of a new type of divacant [α-5,10-P2W16O60]14− fragment, which assembles with Zr4+ ions to form a cyclic trimer. Furthermore, 1 as a heterogeneous catalyst exhibits high activity for the selective oxidative degradation of a sulfur mustard simulant CEES.",

author = "Li, \{Hai Lou\} and Chen Lian and Yang, \{Guo Yu\}",

note = "Publisher Copyright: {\textcopyright} 2023 The Royal Society of Chemistry.",

year = "2022",

month = dec,

day = "22",

doi = "10.1039/d2dt03820j",

language = "English",

volume = "52",

pages = "857--861",

journal = "Dalton Transactions",

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T1 - A Zr-added Dawson-type poly(polyoxometalate)

AU - Li, Hai Lou

AU - Lian, Chen

AU - Yang, Guo Yu

PY - 2022/12/22

Y1 - 2022/12/22

N2 - A novel Zr-added trimer, [H2N(CH3)2]10H14[(Zr2P2W16O61)3]·7H2O (1), has been made under hydrothermal conditions, and contains the highest number of Zr centers in known Dawson-type poly(POM)s. A remarkable feature of this study is the first discovery of a new type of divacant [α-5,10-P2W16O60]14− fragment, which assembles with Zr4+ ions to form a cyclic trimer. Furthermore, 1 as a heterogeneous catalyst exhibits high activity for the selective oxidative degradation of a sulfur mustard simulant CEES.

AB - A novel Zr-added trimer, [H2N(CH3)2]10H14[(Zr2P2W16O61)3]·7H2O (1), has been made under hydrothermal conditions, and contains the highest number of Zr centers in known Dawson-type poly(POM)s. A remarkable feature of this study is the first discovery of a new type of divacant [α-5,10-P2W16O60]14− fragment, which assembles with Zr4+ ions to form a cyclic trimer. Furthermore, 1 as a heterogeneous catalyst exhibits high activity for the selective oxidative degradation of a sulfur mustard simulant CEES.

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DO - 10.1039/d2dt03820j

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SN - 1477-9226

VL - 52

SP - 857

EP - 861

JO - Dalton Transactions

JF - Dalton Transactions

IS - 4

ER -

A Zr-added Dawson-type poly(polyoxometalate)

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