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A two-step field-induced magnetic transition in spin-canted systems observed only for the CoII coordination polymer

  • Hong Peng Jia
  • , Wei Li
  • , Zhan Feng Ju
  • , Jie Zhang*
  • *此作品的通讯作者
  • CAS - Fujian Institute of Research on the Structure of Matter

科研成果: 期刊稿件文章同行评审

摘要

Two isostructural 1D compounds {[M3(hpdc)2(H 2O)6]·2H2O}n (M = Mn, Co; H3hpdc = 2-hydroxypyrimidine-4,6-dicarboxylic acid) were synthesized by the in situ hydrothermal reactions of 2-chloropyrimidine-4,6-dicarboxylic acid with MCl2 (M = Mn, Co) and NaOH; the MnII compound shows spin-canted antiferromagnetism, whereas the CoII compound exhibits the coexistence of spin-canting and a two-step field-induced magnetic phase transition.

源语言英语
页(从-至)371-373
页数3
期刊Chemical Communications
3
DOI
出版状态已出版 - 2008
已对外发布

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