A series of Ni6-substituted polyoxometalates derivated from tripodal alcohol ligands

Xin Xiong Li; Shou Tian Zheng; Wei Hui Fang; Guo Yu Yang

doi:10.1016/j.inoche.2011.06.020

A series of Ni₆-substituted polyoxometalates derivated from tripodal alcohol ligands

Xin Xiong Li
, Shou Tian Zheng
, Wei Hui Fang
, Guo Yu Yang^*

^*此作品的通讯作者

化学与化工学院

CAS - Fujian Institute of Research on the Structure of Matter

科研成果: 期刊稿件 › 文章 › 同行评审

28 引用（Scopus）

摘要

A series of new polyoxometalates based on [Ni₆(μ₃- OH)₃(H₂O)₆(en)₃(B-α-PW ₉O₃₄)] (en = ethylenediamine) clusters capped by different tripodal alcohol ligands have been hydrothermally synthesized and characterized by IR, TGA and single-crystal X-ray diffraction, respectively. The experimental results indicate that the tripodal alcohol ligands can substitute three hydroxyl groups located on the axial positions of the Ni₆ cluster to form new polyoxometalates with different substituted modes.

源语言	英语
页（从-至）	1541-1545
页数	5
期刊	Inorganic Chemistry Communications
卷	14
期	9
DOI	https://doi.org/10.1016/j.inoche.2011.06.020
出版状态	已出版 - 9月 2011

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10.1016/j.inoche.2011.06.020

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@article{cac6c36ee1074b4cb3399ffb87c502f1,

title = "A series of Ni6-substituted polyoxometalates derivated from tripodal alcohol ligands",

abstract = "A series of new polyoxometalates based on [Ni6(μ3- OH)3(H2O)6(en)3(B-α-PW 9O34)] (en = ethylenediamine) clusters capped by different tripodal alcohol ligands have been hydrothermally synthesized and characterized by IR, TGA and single-crystal X-ray diffraction, respectively. The experimental results indicate that the tripodal alcohol ligands can substitute three hydroxyl groups located on the axial positions of the Ni6 cluster to form new polyoxometalates with different substituted modes.",

keywords = "Hydrothermal synthesis, Keggin, Nickel, Polyoxometalates, Tripodal alcohol ligand",

author = "Li, \{Xin Xiong\} and Zheng, \{Shou Tian\} and Fang, \{Wei Hui\} and Yang, \{Guo Yu\}",

year = "2011",

month = sep,

doi = "10.1016/j.inoche.2011.06.020",

language = "English",

volume = "14",

pages = "1541--1545",

journal = "Inorganic Chemistry Communications",

issn = "1387-7003",

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TY - JOUR

T1 - A series of Ni6-substituted polyoxometalates derivated from tripodal alcohol ligands

AU - Li, Xin Xiong

AU - Zheng, Shou Tian

AU - Fang, Wei Hui

AU - Yang, Guo Yu

PY - 2011/9

Y1 - 2011/9

N2 - A series of new polyoxometalates based on [Ni6(μ3- OH)3(H2O)6(en)3(B-α-PW 9O34)] (en = ethylenediamine) clusters capped by different tripodal alcohol ligands have been hydrothermally synthesized and characterized by IR, TGA and single-crystal X-ray diffraction, respectively. The experimental results indicate that the tripodal alcohol ligands can substitute three hydroxyl groups located on the axial positions of the Ni6 cluster to form new polyoxometalates with different substituted modes.

AB - A series of new polyoxometalates based on [Ni6(μ3- OH)3(H2O)6(en)3(B-α-PW 9O34)] (en = ethylenediamine) clusters capped by different tripodal alcohol ligands have been hydrothermally synthesized and characterized by IR, TGA and single-crystal X-ray diffraction, respectively. The experimental results indicate that the tripodal alcohol ligands can substitute three hydroxyl groups located on the axial positions of the Ni6 cluster to form new polyoxometalates with different substituted modes.

KW - Hydrothermal synthesis

KW - Keggin

KW - Nickel

KW - Polyoxometalates

KW - Tripodal alcohol ligand

UR - https://www.scopus.com/pages/publications/79960845910

U2 - 10.1016/j.inoche.2011.06.020

DO - 10.1016/j.inoche.2011.06.020

M3 - Article

AN - SCOPUS:79960845910

SN - 1387-7003

VL - 14

SP - 1541

EP - 1545

JO - Inorganic Chemistry Communications

JF - Inorganic Chemistry Communications

IS - 9

ER -

A series of Ni6-substituted polyoxometalates derivated from tripodal alcohol ligands

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A series of Ni₆-substituted polyoxometalates derivated from tripodal alcohol ligands