A polymorph of cis-dichloridobis(1,10-phenanthroline-k2 N,N′)cobalt(II)

Ling Ling Li; Dong Xia Liu; Tian Fu Liu

doi:10.1107/S1600536807028073

A polymorph of cis-dichloridobis(1,10-phenanthroline-k² N,N′)cobalt(II)

Ling Ling Li
, Dong Xia Liu
, Tian Fu Liu^*

^*此作品的通讯作者

化学与化工学院

Beijing Institute of Technology

科研成果: 期刊稿件 › 文章 › 同行评审

4 引用（Scopus）

摘要

A new polymorph of the title cobalt(II) complex, [CoCl2(C12H8N2)2], is reported here. A previous study reported a monoclinic form of this complex [Zhong, Zeng & Luo (2006), Acta Cryst. E62, m3330-m3332]. In the present orthorhombic structure, the Co^II ion is located in a distorted octa-hedral geometry and coordinated by four N atoms from two 1,10-phenanthroline ligands and two Cl^- anions. The mol-ecules are linked into a two-dimensional framework via weak C - H⋯Cl hydrogen bonding.

源语言	英语
页（从-至）	m1880
期刊	Acta Crystallographica Section E: Structure Reports Online
卷	63
期	7
DOI	https://doi.org/10.1107/S1600536807028073
出版状态	已出版 - 6 6月 2007

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@article{ab8a12830361470db17ac1bebd678bf6,

title = "A polymorph of cis-dichloridobis(1,10-phenanthroline-k2 N,N′)cobalt(II)",

abstract = "A new polymorph of the title cobalt(II) complex, [CoCl2(C12H8N2)2], is reported here. A previous study reported a monoclinic form of this complex [Zhong, Zeng \& Luo (2006), Acta Cryst. E62, m3330-m3332]. In the present orthorhombic structure, the CoII ion is located in a distorted octa-hedral geometry and coordinated by four N atoms from two 1,10-phenanthroline ligands and two Cl- anions. The mol-ecules are linked into a two-dimensional framework via weak C - H⋯Cl hydrogen bonding.",

author = "Li, \{Ling Ling\} and Liu, \{Dong Xia\} and Liu, \{Tian Fu\}",

year = "2007",

month = jun,

day = "6",

doi = "10.1107/S1600536807028073",

language = "English",

volume = "63",

pages = "m1880",

journal = "Acta Crystallographica Section E: Structure Reports Online",

issn = "1600-5368",

publisher = "International Union of Crystallography",

number = "7",

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TY - JOUR

T1 - A polymorph of cis-dichloridobis(1,10-phenanthroline-k2 N,N′)cobalt(II)

AU - Li, Ling Ling

AU - Liu, Dong Xia

AU - Liu, Tian Fu

PY - 2007/6/6

Y1 - 2007/6/6

N2 - A new polymorph of the title cobalt(II) complex, [CoCl2(C12H8N2)2], is reported here. A previous study reported a monoclinic form of this complex [Zhong, Zeng & Luo (2006), Acta Cryst. E62, m3330-m3332]. In the present orthorhombic structure, the CoII ion is located in a distorted octa-hedral geometry and coordinated by four N atoms from two 1,10-phenanthroline ligands and two Cl- anions. The mol-ecules are linked into a two-dimensional framework via weak C - H⋯Cl hydrogen bonding.

AB - A new polymorph of the title cobalt(II) complex, [CoCl2(C12H8N2)2], is reported here. A previous study reported a monoclinic form of this complex [Zhong, Zeng & Luo (2006), Acta Cryst. E62, m3330-m3332]. In the present orthorhombic structure, the CoII ion is located in a distorted octa-hedral geometry and coordinated by four N atoms from two 1,10-phenanthroline ligands and two Cl- anions. The mol-ecules are linked into a two-dimensional framework via weak C - H⋯Cl hydrogen bonding.

UR - https://www.scopus.com/pages/publications/34547201182

U2 - 10.1107/S1600536807028073

DO - 10.1107/S1600536807028073

M3 - Article

AN - SCOPUS:34547201182

SN - 1600-5368

VL - 63

SP - m1880

JO - Acta Crystallographica Section E: Structure Reports Online

JF - Acta Crystallographica Section E: Structure Reports Online

IS - 7

ER -

A polymorph of cis-dichloridobis(1,10-phenanthroline-k2 N,N′)cobalt(II)

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A polymorph of cis-dichloridobis(1,10-phenanthroline-k² N,N′)cobalt(II)