A PdAg bimetallic nanocatalyst for selective reductive amination of nitroarenes

Linsen Li; Zhiqiang Niu; Shuangfei Cai; Yun Zhi; Hao Li; Hongpan Rong; Lichen Liu; Lei Liu; Wei He; Yadong Li

doi:10.1039/c3cc00249g

A PdAg bimetallic nanocatalyst for selective reductive amination of nitroarenes

Linsen Li
, Zhiqiang Niu
, Shuangfei Cai
, Yun Zhi
, Hao Li
, Hongpan Rong
, Lichen Liu
, Lei Liu
, Wei He^*
, Yadong Li

^*此作品的通讯作者

Tsinghua University

科研成果: 期刊稿件 › 文章 › 同行评审

76 引用（Scopus）

摘要

Herein we have identified an optimal catalyst, Pd₁Ag_1.7, for the tandem reductive amination between nitroarenes and aldehydes (selectivity > 93%). Key to the success is the ability to control the compositions of the investigational Pd_1−xAg_x (x = 0–1) catalysts, as well as the clear composition dependent activity/selectivity trend observed in this study. This catalyst features a wide substrate scope, excellent recyclability, activity and selectivity under ambient conditions.

源语言	英语
页（从-至）	6843-6845
页数	3
期刊	Chemical Communications
卷	49
期	61
DOI	https://doi.org/10.1039/c3cc00249g
出版状态	已出版 - 4 7月 2013
已对外发布	是

访问文件

10.1039/c3cc00249g

其它文件与链接

链接到 Scopus 的出版物

引用此

@article{9cd93a10140b4efeb2c10ebe1187ac5a,

title = "A PdAg bimetallic nanocatalyst for selective reductive amination of nitroarenes",

abstract = "Herein we have identified an optimal catalyst, Pd1Ag1.7, for the tandem reductive amination between nitroarenes and aldehydes (selectivity > 93\%). Key to the success is the ability to control the compositions of the investigational Pd1−xAgx (x = 0{\textendash}1) catalysts, as well as the clear composition dependent activity/selectivity trend observed in this study. This catalyst features a wide substrate scope, excellent recyclability, activity and selectivity under ambient conditions.",

author = "Linsen Li and Zhiqiang Niu and Shuangfei Cai and Yun Zhi and Hao Li and Hongpan Rong and Lichen Liu and Lei Liu and Wei He and Yadong Li",

year = "2013",

month = jul,

day = "4",

doi = "10.1039/c3cc00249g",

language = "English",

volume = "49",

pages = "6843--6845",

journal = "Chemical Communications",

issn = "1359-7345",

publisher = "Royal Society of Chemistry",

number = "61",

}

TY - JOUR

T1 - A PdAg bimetallic nanocatalyst for selective reductive amination of nitroarenes

AU - Li, Linsen

AU - Niu, Zhiqiang

AU - Cai, Shuangfei

AU - Zhi, Yun

AU - Li, Hao

AU - Rong, Hongpan

AU - Liu, Lichen

AU - Liu, Lei

AU - He, Wei

AU - Li, Yadong

PY - 2013/7/4

Y1 - 2013/7/4

N2 - Herein we have identified an optimal catalyst, Pd1Ag1.7, for the tandem reductive amination between nitroarenes and aldehydes (selectivity > 93%). Key to the success is the ability to control the compositions of the investigational Pd1−xAgx (x = 0–1) catalysts, as well as the clear composition dependent activity/selectivity trend observed in this study. This catalyst features a wide substrate scope, excellent recyclability, activity and selectivity under ambient conditions.

AB - Herein we have identified an optimal catalyst, Pd1Ag1.7, for the tandem reductive amination between nitroarenes and aldehydes (selectivity > 93%). Key to the success is the ability to control the compositions of the investigational Pd1−xAgx (x = 0–1) catalysts, as well as the clear composition dependent activity/selectivity trend observed in this study. This catalyst features a wide substrate scope, excellent recyclability, activity and selectivity under ambient conditions.

UR - https://www.scopus.com/pages/publications/84879946391

U2 - 10.1039/c3cc00249g

DO - 10.1039/c3cc00249g

M3 - Article

C2 - 23518781

AN - SCOPUS:84879946391

SN - 1359-7345

VL - 49

SP - 6843

EP - 6845

JO - Chemical Communications

JF - Chemical Communications

IS - 61

ER -

A PdAg bimetallic nanocatalyst for selective reductive amination of nitroarenes

摘要

访问文件

其它文件与链接

学术指纹

引用此