A novel ternary energetic compound: DAF/DNP/H2O cocrystal

Xiaopeng Zhang; Yige Wu; Shaohua Jin; Guanchao Lan; Xiaojun Wang; Junfeng Wang; Fenqing Shang; Shusen Chen; Junyi Du; Qinghai Shu

doi:10.1080/07370652.2022.2028035

A novel ternary energetic compound: DAF/DNP/H₂O cocrystal

Xiaopeng Zhang
, Yige Wu
, Shaohua Jin
, Guanchao Lan
, Xiaojun Wang
, Junfeng Wang
, Fenqing Shang
, Shusen Chen
, Junyi Du^*
, Qinghai Shu

^*此作品的通讯作者

材料学院

Nanjing University of Science and Technology
Beijing Institute of Technology
Research Institute of Gansu Yinguang Chemical Industry Group

科研成果: 期刊稿件 › 文章 › 同行评审

1 引用（Scopus）

摘要

A novel ternary energetic cocrystal composed of 3,4-diaminofurazan (DAF), 3,4-dinitropyrazole (DNP), and H₂O in a 1:1:1 stoichiometry with low impact sensitivity is reported. This cocrystal has a predicted detonation velocity higher than DAF and TNT. Preliminary attempts are reported to obtain the even more energetic cocrystals DAF/DNP and DAF/DNP/H₂O₂. For the latter, an original approach based on the urea/H₂O₂ cocrystal as a source of H₂O₂ is described.

源语言	英语
页（从-至）	84-96
页数	13
期刊	Journal of Energetic Materials
卷	42
期	1
DOI	https://doi.org/10.1080/07370652.2022.2028035
出版状态	已出版 - 2024

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10.1080/07370652.2022.2028035

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@article{6237aa9cd2ad4ea38208d258e2924fe7,

title = "A novel ternary energetic compound: DAF/DNP/H2O cocrystal",

abstract = "A novel ternary energetic cocrystal composed of 3,4-diaminofurazan (DAF), 3,4-dinitropyrazole (DNP), and H2O in a 1:1:1 stoichiometry with low impact sensitivity is reported. This cocrystal has a predicted detonation velocity higher than DAF and TNT. Preliminary attempts are reported to obtain the even more energetic cocrystals DAF/DNP and DAF/DNP/H2O2. For the latter, an original approach based on the urea/H2O2 cocrystal as a source of H2O2 is described.",

keywords = "Cocrystal, energetic material, sensitivity, ternary",

author = "Xiaopeng Zhang and Yige Wu and Shaohua Jin and Guanchao Lan and Xiaojun Wang and Junfeng Wang and Fenqing Shang and Shusen Chen and Junyi Du and Qinghai Shu",

note = "Publisher Copyright: {\textcopyright} 2022 Taylor \& Francis Group, LLC.",

year = "2024",

doi = "10.1080/07370652.2022.2028035",

language = "English",

volume = "42",

pages = "84--96",

journal = "Journal of Energetic Materials",

issn = "0737-0652",

publisher = "Taylor and Francis Ltd.",

number = "1",

}

TY - JOUR

T1 - A novel ternary energetic compound

T2 - DAF/DNP/H2O cocrystal

AU - Zhang, Xiaopeng

AU - Wu, Yige

AU - Jin, Shaohua

AU - Lan, Guanchao

AU - Wang, Xiaojun

AU - Wang, Junfeng

AU - Shang, Fenqing

AU - Chen, Shusen

AU - Du, Junyi

AU - Shu, Qinghai

PY - 2024

Y1 - 2024

N2 - A novel ternary energetic cocrystal composed of 3,4-diaminofurazan (DAF), 3,4-dinitropyrazole (DNP), and H2O in a 1:1:1 stoichiometry with low impact sensitivity is reported. This cocrystal has a predicted detonation velocity higher than DAF and TNT. Preliminary attempts are reported to obtain the even more energetic cocrystals DAF/DNP and DAF/DNP/H2O2. For the latter, an original approach based on the urea/H2O2 cocrystal as a source of H2O2 is described.

AB - A novel ternary energetic cocrystal composed of 3,4-diaminofurazan (DAF), 3,4-dinitropyrazole (DNP), and H2O in a 1:1:1 stoichiometry with low impact sensitivity is reported. This cocrystal has a predicted detonation velocity higher than DAF and TNT. Preliminary attempts are reported to obtain the even more energetic cocrystals DAF/DNP and DAF/DNP/H2O2. For the latter, an original approach based on the urea/H2O2 cocrystal as a source of H2O2 is described.

KW - Cocrystal

KW - energetic material

KW - sensitivity

KW - ternary

UR - https://www.scopus.com/pages/publications/85123318490

U2 - 10.1080/07370652.2022.2028035

DO - 10.1080/07370652.2022.2028035

M3 - Article

AN - SCOPUS:85123318490

SN - 0737-0652

VL - 42

SP - 84

EP - 96

JO - Journal of Energetic Materials

JF - Journal of Energetic Materials

IS - 1

ER -

A novel ternary energetic compound: DAF/DNP/H2O cocrystal

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A novel ternary energetic compound: DAF/DNP/H₂O cocrystal