A novel synthetic route to hexanitrohexaazaisowurtzitane

Si Ping Pang; Yong Zhong Yu; Xin Qi Zhao

doi:10.1002/prep.200500039

A novel synthetic route to hexanitrohexaazaisowurtzitane

Si Ping Pang^*
, Yong Zhong Yu
, Xin Qi Zhao

^*此作品的通讯作者

材料学院

Beijing Institute of Technology

科研成果: 期刊稿件 › 文章 › 同行评审

24 引用（Scopus）

摘要

A new, non-hydrogenolytic synthesis of hexanitrohexaazaisowurtzitane (HNIW, 1) has been investigated. The treatment of hexabenzylhexaazaisowurtzitane (HBIW, 2) with potassium permanganate in acetic anhydride resulted in oxidative debenzylation and acetylation to give tetraacetyldibenzylhexaazaisowurtzitane (TADB, 3a) and other intermediates from the oxidation. Subsequent nitrosolysis and nitrolysis of these intermediates with 65% HNO₃/NaNO₂ and 70% HNO₃/AN produced HNIW in fair yield.

源语言	英语
页（从-至）	442-444
页数	3
期刊	Propellants, Explosives, Pyrotechnics
卷	30
期	6
DOI	https://doi.org/10.1002/prep.200500039
出版状态	已出版 - 12月 2005

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title = "A novel synthetic route to hexanitrohexaazaisowurtzitane",

abstract = "A new, non-hydrogenolytic synthesis of hexanitrohexaazaisowurtzitane (HNIW, 1) has been investigated. The treatment of hexabenzylhexaazaisowurtzitane (HBIW, 2) with potassium permanganate in acetic anhydride resulted in oxidative debenzylation and acetylation to give tetraacetyldibenzylhexaazaisowurtzitane (TADB, 3a) and other intermediates from the oxidation. Subsequent nitrosolysis and nitrolysis of these intermediates with 65\% HNO3/NaNO2 and 70\% HNO3/AN produced HNIW in fair yield.",

keywords = "Acetylation, Debenzylation, Hexanitrohexaazaisowurtzitane, Oxidation",

author = "Pang, \{Si Ping\} and Yu, \{Yong Zhong\} and Zhao, \{Xin Qi\}",

year = "2005",

month = dec,

doi = "10.1002/prep.200500039",

language = "English",

volume = "30",

pages = "442--444",

journal = "Propellants, Explosives, Pyrotechnics",

issn = "0721-3115",

publisher = "Wiley-VCH Verlag",

number = "6",

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TY - JOUR

T1 - A novel synthetic route to hexanitrohexaazaisowurtzitane

AU - Pang, Si Ping

AU - Yu, Yong Zhong

AU - Zhao, Xin Qi

PY - 2005/12

Y1 - 2005/12

N2 - A new, non-hydrogenolytic synthesis of hexanitrohexaazaisowurtzitane (HNIW, 1) has been investigated. The treatment of hexabenzylhexaazaisowurtzitane (HBIW, 2) with potassium permanganate in acetic anhydride resulted in oxidative debenzylation and acetylation to give tetraacetyldibenzylhexaazaisowurtzitane (TADB, 3a) and other intermediates from the oxidation. Subsequent nitrosolysis and nitrolysis of these intermediates with 65% HNO3/NaNO2 and 70% HNO3/AN produced HNIW in fair yield.

AB - A new, non-hydrogenolytic synthesis of hexanitrohexaazaisowurtzitane (HNIW, 1) has been investigated. The treatment of hexabenzylhexaazaisowurtzitane (HBIW, 2) with potassium permanganate in acetic anhydride resulted in oxidative debenzylation and acetylation to give tetraacetyldibenzylhexaazaisowurtzitane (TADB, 3a) and other intermediates from the oxidation. Subsequent nitrosolysis and nitrolysis of these intermediates with 65% HNO3/NaNO2 and 70% HNO3/AN produced HNIW in fair yield.

KW - Acetylation

KW - Debenzylation

KW - Hexanitrohexaazaisowurtzitane

KW - Oxidation

UR - https://www.scopus.com/pages/publications/29544436082

U2 - 10.1002/prep.200500039

DO - 10.1002/prep.200500039

M3 - Article

AN - SCOPUS:29544436082

SN - 0721-3115

VL - 30

SP - 442

EP - 444

JO - Propellants, Explosives, Pyrotechnics

JF - Propellants, Explosives, Pyrotechnics

IS - 6

ER -

A novel synthetic route to hexanitrohexaazaisowurtzitane

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