A novel lead borate of NaPb4(H2O)(B5O9)2·BO3 with nonlinear optical property

Guang Huang; Rui Pan; Huan He; Bai Feng Yang; Guo Yu Yang

doi:10.1016/j.inoche.2015.04.021

A novel lead borate of NaPb₄(H₂O)(B₅O₉)₂·BO₃ with nonlinear optical property

Guang Huang
, Rui Pan
, Huan He^*
, Bai Feng Yang
, Guo Yu Yang

^*此作品的通讯作者

化学与化工学院

Beijing Institute of Technology

科研成果: 期刊稿件 › 文章 › 同行评审

1 引用（Scopus）

摘要

A new mixed metal borate, NaPb₄(H₂O)(B₅O₉)₂·BO₃, with an acentric structure has been successfully made under hydrothermal conditions and structurally characterized by IR spectroscopy, powder X-ray diffraction (PXRD), thermogravimetric analysis (TGA) and single-crystal X-ray diffraction, respectively. The structural analysis shows that 1 crystallizes in the orthorhombic space group Pnn2 (No. 34) with a = 11.3724(5) Å, b = 11.4455(4) Å, c = 6.5578(2) Å and Z = 2. In the structure 1, the structural building unit, B₅O₁₂ cluster, connects adjacent six same ones to form a 3-D oxoboron framework with 8-membered ring (MR) and 10-MR channels along the c-axis. The Pb atoms and coordinated water molecules are located in the 8-MR channels, while the 10-MR channels were occupied by the chains built by Na atoms and the BO₃ groups. Second-harmonic generation (SHG) measurements on the powder samples reveal that 1 exhibits SHG efficiency approximately 2 times that of KH₂PO₄ (KDP). Also it has a UV cutoff edge below 220 nm.

源语言	英语
页（从-至）	17-20
页数	4
期刊	Inorganic Chemistry Communications
卷	59
DOI	https://doi.org/10.1016/j.inoche.2015.04.021
出版状态	已出版 - 29 6月 2015

访问文件

10.1016/j.inoche.2015.04.021

其它文件与链接

链接到 Scopus 的出版物

引用此

@article{0a3319370b6d453ba5cdb8a46472e67c,

title = "A novel lead borate of NaPb4(H2O)(B5O9)2·BO3 with nonlinear optical property",

abstract = "A new mixed metal borate, NaPb4(H2O)(B5O9)2·BO3, with an acentric structure has been successfully made under hydrothermal conditions and structurally characterized by IR spectroscopy, powder X-ray diffraction (PXRD), thermogravimetric analysis (TGA) and single-crystal X-ray diffraction, respectively. The structural analysis shows that 1 crystallizes in the orthorhombic space group Pnn2 (No. 34) with a = 11.3724(5) {\AA}, b = 11.4455(4) {\AA}, c = 6.5578(2) {\AA} and Z = 2. In the structure 1, the structural building unit, B5O12 cluster, connects adjacent six same ones to form a 3-D oxoboron framework with 8-membered ring (MR) and 10-MR channels along the c-axis. The Pb atoms and coordinated water molecules are located in the 8-MR channels, while the 10-MR channels were occupied by the chains built by Na atoms and the BO3 groups. Second-harmonic generation (SHG) measurements on the powder samples reveal that 1 exhibits SHG efficiency approximately 2 times that of KH2PO4 (KDP). Also it has a UV cutoff edge below 220 nm.",

keywords = "Borate, Cluster, Crystal structure, Hydrothermal syntheses, Nonlinear optical",

author = "Guang Huang and Rui Pan and Huan He and Yang, \{Bai Feng\} and Yang, \{Guo Yu\}",

year = "2015",

month = jun,

day = "29",

doi = "10.1016/j.inoche.2015.04.021",

language = "English",

volume = "59",

pages = "17--20",

journal = "Inorganic Chemistry Communications",

issn = "1387-7003",

publisher = "Elsevier B.V.",

}

TY - JOUR

T1 - A novel lead borate of NaPb4(H2O)(B5O9)2·BO3 with nonlinear optical property

AU - Huang, Guang

AU - Pan, Rui

AU - He, Huan

AU - Yang, Bai Feng

AU - Yang, Guo Yu

PY - 2015/6/29

Y1 - 2015/6/29

N2 - A new mixed metal borate, NaPb4(H2O)(B5O9)2·BO3, with an acentric structure has been successfully made under hydrothermal conditions and structurally characterized by IR spectroscopy, powder X-ray diffraction (PXRD), thermogravimetric analysis (TGA) and single-crystal X-ray diffraction, respectively. The structural analysis shows that 1 crystallizes in the orthorhombic space group Pnn2 (No. 34) with a = 11.3724(5) Å, b = 11.4455(4) Å, c = 6.5578(2) Å and Z = 2. In the structure 1, the structural building unit, B5O12 cluster, connects adjacent six same ones to form a 3-D oxoboron framework with 8-membered ring (MR) and 10-MR channels along the c-axis. The Pb atoms and coordinated water molecules are located in the 8-MR channels, while the 10-MR channels were occupied by the chains built by Na atoms and the BO3 groups. Second-harmonic generation (SHG) measurements on the powder samples reveal that 1 exhibits SHG efficiency approximately 2 times that of KH2PO4 (KDP). Also it has a UV cutoff edge below 220 nm.

AB - A new mixed metal borate, NaPb4(H2O)(B5O9)2·BO3, with an acentric structure has been successfully made under hydrothermal conditions and structurally characterized by IR spectroscopy, powder X-ray diffraction (PXRD), thermogravimetric analysis (TGA) and single-crystal X-ray diffraction, respectively. The structural analysis shows that 1 crystallizes in the orthorhombic space group Pnn2 (No. 34) with a = 11.3724(5) Å, b = 11.4455(4) Å, c = 6.5578(2) Å and Z = 2. In the structure 1, the structural building unit, B5O12 cluster, connects adjacent six same ones to form a 3-D oxoboron framework with 8-membered ring (MR) and 10-MR channels along the c-axis. The Pb atoms and coordinated water molecules are located in the 8-MR channels, while the 10-MR channels were occupied by the chains built by Na atoms and the BO3 groups. Second-harmonic generation (SHG) measurements on the powder samples reveal that 1 exhibits SHG efficiency approximately 2 times that of KH2PO4 (KDP). Also it has a UV cutoff edge below 220 nm.

KW - Borate

KW - Cluster

KW - Crystal structure

KW - Hydrothermal syntheses

KW - Nonlinear optical

UR - https://www.scopus.com/pages/publications/84933051783

U2 - 10.1016/j.inoche.2015.04.021

DO - 10.1016/j.inoche.2015.04.021

M3 - Article

AN - SCOPUS:84933051783

SN - 1387-7003

VL - 59

SP - 17

EP - 20

JO - Inorganic Chemistry Communications

JF - Inorganic Chemistry Communications

ER -

A novel lead borate of NaPb4(H2O)(B5O9)2·BO3 with nonlinear optical property

摘要

访问文件

其它文件与链接

指纹

引用此

A novel lead borate of NaPb₄(H₂O)(B₅O₉)₂·BO₃ with nonlinear optical property