TY - JOUR
T1 - A novel cellulose-based Azide energetic material
T2 - 1-Azido-2-hydroxypropyl cellulose ether
AU - Yang, Fei Fei
AU - Shao, Ziqiang
AU - Li, Nian Ke
AU - Wang, Fei Jun
AU - Zhang, Youde
PY - 2011/7
Y1 - 2011/7
N2 - 1-azido-2-hydroxypropyl cellulose ether, a novel potential energetic material, was prepared by reacting cellulose with glycidyl azide, which is synthesized from epihalohydrin via ring-opening and ring-closing reactions in the presence of diazoimide, under an alkaline condition, wherein a degree of substitution of the azido side chains as high as 0.5 and a nitrogen content of 10% (mass percentage) were achieved in the 1-azido-2-hydroxypropyl cellulose ether thus obtained. The structure and degree of substitution of the product were identified by characterizations such as elemental analysis, infrared absorption spectrum (IR), thermogravimetric analysis (TG), and nuclear magnetic resonance (NMR).
AB - 1-azido-2-hydroxypropyl cellulose ether, a novel potential energetic material, was prepared by reacting cellulose with glycidyl azide, which is synthesized from epihalohydrin via ring-opening and ring-closing reactions in the presence of diazoimide, under an alkaline condition, wherein a degree of substitution of the azido side chains as high as 0.5 and a nitrogen content of 10% (mass percentage) were achieved in the 1-azido-2-hydroxypropyl cellulose ether thus obtained. The structure and degree of substitution of the product were identified by characterizations such as elemental analysis, infrared absorption spectrum (IR), thermogravimetric analysis (TG), and nuclear magnetic resonance (NMR).
KW - 1-azido-2-hydroxypropyl cellulose ether
KW - Azide
KW - Cellulose derivatives
KW - Energetic materials
UR - https://www.scopus.com/pages/publications/79958184024
U2 - 10.1080/07370652.2010.523755
DO - 10.1080/07370652.2010.523755
M3 - Article
AN - SCOPUS:79958184024
SN - 0737-0652
VL - 29
SP - 241
EP - 260
JO - Journal of Energetic Materials
JF - Journal of Energetic Materials
IS - 3
ER -