摘要
A new layered aluminoborate [Zn(dien)2][{Al(OH)}{B 5O9F}] (1, en = diethylenetriamine) with an acentric structure has been yielded under solvothermal conditions. In 1, the AlO 3(OH) tetrahedra and B5O9F clusters interconnect to form a layer of [{Al(OH)}{B5O9F}] 2- with 7-MR helical channels. 1 exhibits weak SHG properties and luminescence emission at 450 nm.
| 源语言 | 英语 |
|---|---|
| 页(从-至) | 2597-2600 |
| 页数 | 4 |
| 期刊 | CrystEngComm |
| 卷 | 11 |
| 期 | 12 |
| DOI | |
| 出版状态 | 已出版 - 2009 |
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