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A new layered aluminoborate [Zn(dien)2][{Al(OH)}{B 5O9F}] templated by transition metal complexes

  • Jian Zhou
  • , Shou Tian Zheng
  • , Mingyi Zhang
  • , Guang Zhen Liu
  • , Guo Yu Yang*
  • *此作品的通讯作者
  • CAS - Fujian Institute of Research on the Structure of Matter

科研成果: 期刊稿件 › 文章 › 同行评审

摘要

A new layered aluminoborate [Zn(dien)2][{Al(OH)}{B 5O9F}] (1, en = diethylenetriamine) with an acentric structure has been yielded under solvothermal conditions. In 1, the AlO 3(OH) tetrahedra and B5O9F clusters interconnect to form a layer of [{Al(OH)}{B5O9F}] 2- with 7-MR helical channels. 1 exhibits weak SHG properties and luminescence emission at 450 nm.

源语言英语
页(从-至)2597-2600
页数4
期刊CrystEngComm
卷11
期12
DOI
出版状态已出版 - 2009

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