A new efficient route for the synthesis of 4,4′,6,6′-tetra(azido)azo-1,3,5-triazine

Xiao Tong Li; Sheng Hua Li; Si Ping Pang; Yong Zhong Yu; Yun Jun Luo

doi:10.1016/j.cclet.2007.06.028

A new efficient route for the synthesis of 4,4′,6,6′-tetra(azido)azo-1,3,5-triazine

Xiao Tong Li
, Sheng Hua Li
, Si Ping Pang^*
, Yong Zhong Yu
, Yun Jun Luo

^*此作品的通讯作者

材料学院

Beijing Institute of Technology

科研成果: 期刊稿件 › 文章 › 同行评审

19 引用（Scopus）

摘要

A new method for the synthesis of 4,4′,6,6′-tetra(azido)azo-1,3,5-triazine (TAAT) is described. The key intermediate 4,4′,6,6′-tetra(azido)hydrazo-1,3,5-triazine (TAHT) was synthesized by nucleophilic substitution in the case of sodium azide as nucleophile. N-Bromosuccinide (NBS) was used as oxidant to oxidize TAHT by a tractable operation under mild reaction condition. The target compound TAAT was obtained with a facile process and high overall yield of 81%. The structures of TAAT and its intermediates were identified by spectroscopic methods.

源语言	英语
页（从-至）	1037-1039
页数	3
期刊	Chinese Chemical Letters
卷	18
期	9
DOI	https://doi.org/10.1016/j.cclet.2007.06.028
出版状态	已出版 - 9月 2007

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10.1016/j.cclet.2007.06.028

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@article{06d90eedc65c479cbf2ba841afbc4781,

title = "A new efficient route for the synthesis of 4,4′,6,6′-tetra(azido)azo-1,3,5-triazine",

abstract = "A new method for the synthesis of 4,4′,6,6′-tetra(azido)azo-1,3,5-triazine (TAAT) is described. The key intermediate 4,4′,6,6′-tetra(azido)hydrazo-1,3,5-triazine (TAHT) was synthesized by nucleophilic substitution in the case of sodium azide as nucleophile. N-Bromosuccinide (NBS) was used as oxidant to oxidize TAHT by a tractable operation under mild reaction condition. The target compound TAAT was obtained with a facile process and high overall yield of 81\%. The structures of TAAT and its intermediates were identified by spectroscopic methods.",

keywords = "Azide, High-nitrogen compounds, Synthesis, Triazine",

author = "Li, \{Xiao Tong\} and Li, \{Sheng Hua\} and Pang, \{Si Ping\} and Yu, \{Yong Zhong\} and Luo, \{Yun Jun\}",

year = "2007",

month = sep,

doi = "10.1016/j.cclet.2007.06.028",

language = "English",

volume = "18",

pages = "1037--1039",

journal = "Chinese Chemical Letters",

issn = "1001-8417",

publisher = "Elsevier B.V.",

number = "9",

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TY - JOUR

T1 - A new efficient route for the synthesis of 4,4′,6,6′-tetra(azido)azo-1,3,5-triazine

AU - Li, Xiao Tong

AU - Li, Sheng Hua

AU - Pang, Si Ping

AU - Yu, Yong Zhong

AU - Luo, Yun Jun

PY - 2007/9

Y1 - 2007/9

N2 - A new method for the synthesis of 4,4′,6,6′-tetra(azido)azo-1,3,5-triazine (TAAT) is described. The key intermediate 4,4′,6,6′-tetra(azido)hydrazo-1,3,5-triazine (TAHT) was synthesized by nucleophilic substitution in the case of sodium azide as nucleophile. N-Bromosuccinide (NBS) was used as oxidant to oxidize TAHT by a tractable operation under mild reaction condition. The target compound TAAT was obtained with a facile process and high overall yield of 81%. The structures of TAAT and its intermediates were identified by spectroscopic methods.

AB - A new method for the synthesis of 4,4′,6,6′-tetra(azido)azo-1,3,5-triazine (TAAT) is described. The key intermediate 4,4′,6,6′-tetra(azido)hydrazo-1,3,5-triazine (TAHT) was synthesized by nucleophilic substitution in the case of sodium azide as nucleophile. N-Bromosuccinide (NBS) was used as oxidant to oxidize TAHT by a tractable operation under mild reaction condition. The target compound TAAT was obtained with a facile process and high overall yield of 81%. The structures of TAAT and its intermediates were identified by spectroscopic methods.

KW - Azide

KW - High-nitrogen compounds

KW - Synthesis

KW - Triazine

UR - https://www.scopus.com/pages/publications/34548236945

U2 - 10.1016/j.cclet.2007.06.028

DO - 10.1016/j.cclet.2007.06.028

M3 - Article

AN - SCOPUS:34548236945

SN - 1001-8417

VL - 18

SP - 1037

EP - 1039

JO - Chinese Chemical Letters

JF - Chinese Chemical Letters

IS - 9

ER -

A new efficient route for the synthesis of 4,4′,6,6′-tetra(azido)azo-1,3,5-triazine

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