A molecularly engineered siloxane-derived hybrid interphase for dendrite-free all-solid-state lithium metal batteries

Kun Song; Tong Liu; Siwu Li; Jun Liu; Haitao Chen; Qianyou Wang; Weiwei Wu; Chuang Yu

doi:10.1039/d6cc04347j

A molecularly engineered siloxane-derived hybrid interphase for dendrite-free all-solid-state lithium metal batteries

Kun Song
, Tong Liu
, Siwu Li^*
, Jun Liu
, Haitao Chen
, Qianyou Wang
, Weiwei Wu^*
, Chuang Yu^*

^*此作品的通讯作者

机电学院

Xidian University
Shanghai Institute of Space Power Sources

科研成果: 期刊稿件 › 文章 › 同行评审

摘要

A fluorinated siloxane-derived hybrid interphase featuring molecularly dispersed LiF/LiIn nanodomains in a cross-linked polysiloxane network is constructed on Li metal via co-reduction of a fluorinated alkoxysilane and InCl₃. The elastic organic matrix accommodates volume fluctuations, while inorganic components suppress dendrites and enhance Li⁺ transport, enabling a critical current density of 3.2 mA cm⁻² and 78.7% capacity retention after 200 cycles at 0.5C in sulfide all-solid-state full cells.

源语言	英语
页（从-至）	18459-18463
页数	5
期刊	Chemical Communications
卷	62
期	74
DOI	https://doi.org/10.1039/d6cc04347j
出版状态	已出版 - 22 9月 2026

访问文件

10.1039/d6cc04347j

其它文件与链接

链接到 Scopus 的出版物

引用此

@article{1b5653b65831463e89ee86261b85c48a,

title = "A molecularly engineered siloxane-derived hybrid interphase for dendrite-free all-solid-state lithium metal batteries",

abstract = "A fluorinated siloxane-derived hybrid interphase featuring molecularly dispersed LiF/LiIn nanodomains in a cross-linked polysiloxane network is constructed on Li metal via co-reduction of a fluorinated alkoxysilane and InCl3. The elastic organic matrix accommodates volume fluctuations, while inorganic components suppress dendrites and enhance Li+ transport, enabling a critical current density of 3.2 mA cm−2 and 78.7\% capacity retention after 200 cycles at 0.5C in sulfide all-solid-state full cells.",

author = "Kun Song and Tong Liu and Siwu Li and Jun Liu and Haitao Chen and Qianyou Wang and Weiwei Wu and Chuang Yu",

note = "Publisher Copyright: This journal is {\textcopyright} The Royal Society of Chemistry, 2026.",

year = "2026",

month = sep,

day = "22",

doi = "10.1039/d6cc04347j",

language = "English",

volume = "62",

pages = "18459--18463",

journal = "Chemical Communications",

issn = "1359-7345",

publisher = "Royal Society of Chemistry",

number = "74",

}

TY - JOUR

T1 - A molecularly engineered siloxane-derived hybrid interphase for dendrite-free all-solid-state lithium metal batteries

AU - Song, Kun

AU - Liu, Tong

AU - Li, Siwu

AU - Liu, Jun

AU - Chen, Haitao

AU - Wang, Qianyou

AU - Wu, Weiwei

AU - Yu, Chuang

PY - 2026/9/22

Y1 - 2026/9/22

N2 - A fluorinated siloxane-derived hybrid interphase featuring molecularly dispersed LiF/LiIn nanodomains in a cross-linked polysiloxane network is constructed on Li metal via co-reduction of a fluorinated alkoxysilane and InCl3. The elastic organic matrix accommodates volume fluctuations, while inorganic components suppress dendrites and enhance Li+ transport, enabling a critical current density of 3.2 mA cm−2 and 78.7% capacity retention after 200 cycles at 0.5C in sulfide all-solid-state full cells.

AB - A fluorinated siloxane-derived hybrid interphase featuring molecularly dispersed LiF/LiIn nanodomains in a cross-linked polysiloxane network is constructed on Li metal via co-reduction of a fluorinated alkoxysilane and InCl3. The elastic organic matrix accommodates volume fluctuations, while inorganic components suppress dendrites and enhance Li+ transport, enabling a critical current density of 3.2 mA cm−2 and 78.7% capacity retention after 200 cycles at 0.5C in sulfide all-solid-state full cells.

UR - https://www.scopus.com/pages/publications/105048290973

U2 - 10.1039/d6cc04347j

DO - 10.1039/d6cc04347j

M3 - Article

C2 - 42640051

AN - SCOPUS:105048290973

SN - 1359-7345

VL - 62

SP - 18459

EP - 18463

JO - Chemical Communications

JF - Chemical Communications

IS - 74

ER -

A molecularly engineered siloxane-derived hybrid interphase for dendrite-free all-solid-state lithium metal batteries

摘要

访问文件

其它文件与链接

学术指纹

引用此